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Article Dans Une Revue Journal of Materials Science and Chemical Engineering Année : 2020

Synthesis and Characterization of the Thermoelectric Nickel Tetrathiooxalate Polymer as Nanoparticles

Résumé

Nanoparticles of the conductive coordination polymer Ni(tto) have been synthesized under mild conditions in the presence of bio-based polyesters or polyethylene glycol acting as growth controlling agents. With polyesters, aggregates of particles are observed whereas well dispersed nanoparticles are obtained with polyethylene glycol. Indeed, for a Ni2+/polyethylene glycol weight ratio of 0.031, transmission electron micrographs evidence dispersed particles exhibiting sizes in the 3 - 10 nm range. Infrared spectra for nanopowders show two CS stretching modes in the 1100 - 1190 cm−1 range, confirming the presence of the tetrathiooxalate ligand coordinated to the nickel center. The room-temperature electrical conductivity for the nanopowder prepared in the presence of polyethylene glycol is about 0.8 S∙cm−1, a decent value for tetrathiolate-based polymers. Finally, magnetic susceptibility measurements for well-dispersed Ni(tto) particles evidence a Curie-Weiss law in a large temperature range. Moreover, low temperatures measurement would confirm intra- or interchain interactions between nickel atoms within the Ni(tto) polymer chains.
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Dates et versions

hal-03981015 , version 1 (06-06-2023)

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Christophe Faulmann, Benoît Cormary, Dominique de Caro, Kane Jacob, Lydie Valade, et al.. Synthesis and Characterization of the Thermoelectric Nickel Tetrathiooxalate Polymer as Nanoparticles. Journal of Materials Science and Chemical Engineering, 2020, 08 (04), pp.1-12. ⟨10.4236/msce.2020.84001⟩. ⟨hal-03981015⟩
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