N-Metallocenyl Ynamides: Preparation, Reactivity and Synthesis of ansa[3]-Ferrocenylamides
Résumé
The first synthesis of various N-metallocenyl ynamides has been developed and two strategies for the oxidative cyclization of N-ferrocenyl ynamide into ansa[3]-ferrocenylamide are also reported. The mechanism for the iodine(III)-triggered transformation has been studied by means of DFT calculations, showing that it proceeds through a Concerted Iodination Deprotonation step. 1
Domaines
Chimie organiqueOrigine | Fichiers produits par l'(les) auteur(s) |
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