N-Metallocenyl Ynamides: Preparation, Reactivity and Synthesis of ansa[3]-Ferrocenylamides - Archive ouverte HAL
Article Dans Une Revue Organic Letters Année : 2023

N-Metallocenyl Ynamides: Preparation, Reactivity and Synthesis of ansa[3]-Ferrocenylamides

Résumé

The first synthesis of various N-metallocenyl ynamides has been developed and two strategies for the oxidative cyclization of N-ferrocenyl ynamide into ansa[3]-ferrocenylamide are also reported. The mechanism for the iodine(III)-triggered transformation has been studied by means of DFT calculations, showing that it proceeds through a Concerted Iodination Deprotonation step. 1

Domaines

Chimie organique
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Dates et versions

hal-03966748 , version 1 (31-01-2023)

Identifiants

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Capucine Mahe, Olivier Blacque, Gilles Gasser, Vincent Gandon, Kevin Cariou. N-Metallocenyl Ynamides: Preparation, Reactivity and Synthesis of ansa[3]-Ferrocenylamides. Organic Letters, 2023, ⟨10.1021/acs.orglett.2c04169⟩. ⟨hal-03966748⟩
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