A stable and photoreactive copper-iodide cubane suitable for direct post-functionalization
Résumé
Tetranuclear copper-iodide cluster consisting of a {Cu4I4} cubane and diphenylphosphine ligand has been found as a highly stable precursor for further post-functionalization through hydrophosphination reaction. UV irradiation of the cluster in the presence of various alkenes allows direct functionalization of the latter, giving access to a wide range of copper cubane complexes, a source of molecular diversity for luminescent materials. Such a strategy provided access to the first example of water-soluble luminescent cubane copper iodide.
Domaines
Chimie| Origine | Fichiers produits par l'(les) auteur(s) |
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