A stable and photoreactive copper-iodide cubane suitable for direct post-functionalization - Archive ouverte HAL Access content directly
Journal Articles European Journal of Inorganic Chemistry Year : 2022

A stable and photoreactive copper-iodide cubane suitable for direct post-functionalization

Abstract

Tetranuclear copper-iodide cluster consisting of a {Cu4I4} cubane and diphenylphosphine ligand has been found as a highly stable precursor for further post-functionalization through hydrophosphination reaction. UV irradiation of the cluster in the presence of various alkenes allows direct functionalization of the latter, giving access to a wide range of copper cubane complexes, a source of molecular diversity for luminescent materials. Such a strategy provided access to the first example of water-soluble luminescent cubane copper iodide.
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Dates and versions

hal-03871610 , version 1 (25-11-2022)

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Damien Bissessar, Julien Egly, Thierry Achard, Pascal Steffanut, Matteo Mauro, et al.. A stable and photoreactive copper-iodide cubane suitable for direct post-functionalization. European Journal of Inorganic Chemistry, 2022, 2022 (15), ⟨10.1002/ejic.202200101⟩. ⟨hal-03871610⟩
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