Organophotocatalysis Enables the Synthesis of gem-FluoroPhosphonate Alkenes
Résumé
gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10methylacridinium perchlorate) as organic photocatalyst, to provide valuables gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were obtained in good to excellent yields and the reaction showed very good chemical tolerance. .
Domaines
Chimie| Origine | Fichiers produits par l'(les) auteur(s) |
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