Metallic Trace Elements Shipping Profile by PM1 Source Apportionment in a Mediterranean Port City
Résumé
Shipping emissions in ports can have substantial impacts on air quality and population health in the nearby urban
environment. Legislative efforts made in recent years have reduced emissions of some gaseous pollutants but the
aerosol chemical composition, in particular metals composition in submicronic fraction, is little documented.
More than 30 trace metals have been monitored with two online metals analysers (Xact 625i) in addition to regulated
pollutants (PM2.5, PM10, NOX, O3 and SO2) and ultrafine particle number during two intensive campaigns in Marseille
(France) in the summer 2021. Samples were taken simultaneously along the port berths and on the urban background
aerosol site MRS-LCP located 2 km from the port. As the second largest city of France, Marseille represents a
challenging environment for source apportionment (SA), as it combines multiple anthropogenic sources including
intensive traffic and various industrial activities in addition to shipping.
This work presents the SA analysis performed on trace elements using Positive Matrix Factorization (PMF) resolved
with the multilinear engine approach (SoFi Pro) on both sampling sites.
Inside the port area, the half hourly metals measurements allowed to define a “shipping” profile by SA analysis. This
profile is dominated by Vanadium (V) and Nickel (Ni) and is associated with ultrafine particles (Dmob<70 nm). On a daily
scale, the profile correlates with ship arrivals and departures.
On the background urban site, PMF results from the summer 2019 showed that a shipping factor enriched in V and Ni
could be retrieved. The use of the shipping profile determined inside the port area to constrain PMF run allowed to
better assess the contribution of this source on air quality. In addition, sources profile comparison between summer
2019 and 2021 highlights the evolution of shipping emissions following the 0.5% fuels sulfur limit implemented in
2020.
Origine | Fichiers produits par l'(les) auteur(s) |
---|