Photocatalyzed Decarboxylation of Oxamic acids Under Near-Infrared Conditions - Archive ouverte HAL
Article Dans Une Revue Chemical Communications Année : 2022

Photocatalyzed Decarboxylation of Oxamic acids Under Near-Infrared Conditions

Résumé

Photocatalyzed oxidative decarboxylation of oxamic acids under nearinfrared irradiation using Os(bptpy)2(PF6)2 as catalyst is reported. The reaction was applied to the synthesis of urethanes and heterocyclic amides. Mechanistic studies and comparative penetration depths between the NIR and the visible light mediated processes are discussed.

Domaines

Chimie organique
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Dates et versions

hal-03853100 , version 1 (15-11-2022)

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Ikechukwu Martin Ogbu, Dario Bassani, Frédéric Robert, Yannick Landais. Photocatalyzed Decarboxylation of Oxamic acids Under Near-Infrared Conditions. Chemical Communications, 2022, 58 (63), pp.8802-8805. ⟨10.1039/d2cc03155h⟩. ⟨hal-03853100⟩
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