Two Different Compounds in One Crystal: di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Chemical Crystallography Année : 2023

Two Different Compounds in One Crystal: di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II)

Résumé

The crystal structures of di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)] diplatinum(II) (1) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) (2) have been determined by means of the X-ray diffraction. Both complexes cocrystallize in the monoclinic space group C2/c with a = 39.5457(18) Å, b = 7.2482(4) Å, c = 21.2269(10) Å and β = 121.460(2)°. The asymmetric unit consists of half a centrosymmetric compound (complex 1) and one full independent compound (complex 2).
Fichier principal
Vignette du fichier
Sasaki, Two different compounds in one crystal, 2022.pdf (4.64 Mo) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)

Dates et versions

hal-03846487 , version 1 (10-11-2022)

Identifiants

Citer

Isabelle Sasaki, Sonia Mallet-Ladeira. Two Different Compounds in One Crystal: di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II). Journal of Chemical Crystallography, 2023, 53, pp.293-298. ⟨10.1007/s10870-022-00970-0⟩. ⟨hal-03846487⟩
51 Consultations
19 Téléchargements

Altmetric

Partager

Gmail Mastodon Facebook X LinkedIn More