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Journal Articles Polymer Chemistry Year : 2022

Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate

Abstract

The radical ring-opening copolymerisation of unsubstituted thionolactones of different ring sizes has been investigated. DFT calculations and experimental results show the importance of the stabilization of the intermediate ring-retained radical.
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hal-03846177 , version 1 (10-11-2022)

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Oleksandr Ivanchenko, Stéphane Mazières, Rinaldo Poli, Simon Harrisson, Mathias Destarac. Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate. Polymer Chemistry, 2022, 13 (45), pp.6284-6292. ⟨10.1039/d2py01153k⟩. ⟨hal-03846177⟩
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