Tungsten and molybdenum dinitrogen complexes supported by a pentadentate tetrapodal phosphine ligand: comparative spectroscopic, electrochemical and reactivity studies
Résumé
The tungsten dinitrogen complex [W(N 2 )(P Me 2 PP Ph 2 )] is compared to its molybdenum analogue. Detailed (IR-spectro)electrochemical investigations were made. In the presence of SmI 2 /H 2 O the W complex mediates the conversion of N 2 to 2.75 equiv. ammonia.
Domaines
Chimie de coordinationOrigine | Fichiers produits par l'(les) auteur(s) |
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