A roadmap to estimating agricultural ammonia volatilization over Europe using satellite observations and simulation data
Abstract
Ammonia (NH3) is one of the most important gases emitted from agricultural practices. It affects air
quality and the overall climate and is in turn influenced by long-term climate trends as well as by short-term
fluctuations in local and regional meteorology. Previous studies have established the capability of the Infrared
Atmospheric Sounding Interferometer (IASI) series of instruments, aboard the Metop satellites, to measure am-
monia from space since 2007. In this study, we explore the interactions between atmospheric ammonia, land and
meteorological variability, and long-term climate trends in Europe. We investigate the emission potential (0soil)
of ammonia from the soil, which describes the soil–atmosphere ammonia exchange. 0soil is generally calcu-
lated in-field or in laboratory experiments; here, and for the first time, we investigate a method which assesses it
remotely using satellite data, reanalysis data products, and model simulations.
We focus on ammonia emission potential in March 2011, which marks the start of growing season in Europe.
Our results show that 0soil ranges from 2 × 103 to 9.5 × 104 (dimensionless) in fertilized cropland, such as in
the North European Plain, and is of the order of 10–102 in a non-fertilized soil (e.g., forest and grassland). These
results agree with in-field measurements from the literature, suggesting that our method can be used in other
seasons and regions in the world. However, some improvements are needed in the determination of mass transfer
coefficient k (m s−1), which is a crucial parameter to derive 0soil.
Using a climate model, we estimate the expected increase in ammonia columns by the end of the century
based on the increase in skin temperature (Tskin), under two different climate scenarios. Ammonia columns are
projected to increase by up to 50 %, particularly in eastern Europe, under the SSP2-4.5 scenario and might
even double (increase of 100 %) under the SSP5-8.5 scenario. The increase in skin temperature is responsible
for a formation of new hotspots of ammonia in Belarus, Ukraine, Hungary, Moldova, parts of Romania, and
Switzerland.
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