Same ligand, three first-row metals: comparing M-amido bifunctional reactivity (Mn, Fe, Co)
Résumé
Three analogous M(SNS) 2 complexes with bifunctional amido donors were used to compare reactivity across the base metals (M = Mn, Fe, Co). Experimental studies support DFT findings in which only the Mn complex can facilitate bifunctional H2 activation.
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