A comprehensive continuum theory of structured liquids - Archive ouverte HAL
Pré-Publication, Document De Travail Année : 2022

A comprehensive continuum theory of structured liquids

R Podgornik
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Résumé

We develop a comprehensive continuum model capable of treating both electrostatic and structural interactions in liquid dielectrics. Starting from a twoorder parameter description in terms of charge density and polarization, we derive a field-theoretic model generalizing previous theories. Our theory explicitly includes electrostatic and structural interactions in the bulk of the liquid and allows for polarization charges within a Drude model. In particular, we develop a detailed description of the boundary conditions which include the charge regulation mechanism and surface polarization. The general features for solving the saddle-point equations of our model are elucidated and future applications to predict and validate experimental results are outlined.
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Dates et versions

hal-03819365 , version 1 (18-10-2022)

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  • HAL Id : hal-03819365 , version 1

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R Blossey, R Podgornik. A comprehensive continuum theory of structured liquids. 2022. ⟨hal-03819365⟩

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