Design of Coordination Polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(II), Zn(II), Cd(II) and Co(II) - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue CrystEngComm Année : 2022

Design of Coordination Polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(II), Zn(II), Cd(II) and Co(II)

Résumé

Five new supramolecular coordination polymers (L-Cu(acac)2, L-Cu(hfac)2, L-ZnCl2, L-CdI2 and L-CoCl2) based on the use of the flexible organic ligand L (1,2-Diphenylethane-1,2-diyl diisonicotinate) combined with Cu(acac)2, Cu(hfac)2, ZnCl2, CdI2 or CoCl2 metallaligands, were synthesized and structurally characterized by single-crystal X-ray diffraction. They represent the first reported coordination polymers based on this ligand presenting ether junctions. X-ray diffraction analysis revealed the structure and the dimensionality of these coordination polymers as well as their packing in the crystal that depends on the conformation adopted by the ligand L and the nature of the metallic salts
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Dates et versions

hal-03807759 , version 1 (10-10-2022)
hal-03807759 , version 2 (12-10-2022)

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Sofia Zazouli, Nathalie Kyritsakas, Veronique Bulach, Sylvie Ferlay, Abdelaziz Jouaiti. Design of Coordination Polymers based on combinations of 1,2-diphenylethane-1,2-diyl diisonicotinate with Cu(II), Zn(II), Cd(II) and Co(II). CrystEngComm, 2022, 24 (43), pp.7632-7639. ⟨10.1039/D2CE01001A⟩. ⟨hal-03807759v2⟩
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