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Article Dans Une Revue European Polymer Journal Année : 2022

Development of molecularly imprinted polymer for the selective recognition of the weakly interacting fenamiphos molecule

Résumé

The possible manufacture of Molecularly Imprinted Polymers (MIPs) under the conditions of weak interaction between the functional monomer and template molecule is addressed with the help of the case of the Fenamiphos organophosphorus insecticide. The choice of the functional monomer is addressed by investigating MIPs prepared by the surface imprinting technique using three very different types of monomers (methacrylic acid, 4-vinylpyridine and 2–(methacryloyloxyethyl)trimethylammonium chloride), a solid silica support grafted with 3-mercaptopropyltrimethoxysilane on its surface; ethylene glycol dimethacrylate as the cross-linker and acetonitrile as solvent. The prepared materials were characterized by IR, solid state 13C NMR, TGA, DLS, BET and TEM. Their performance as adsorbents were evaluated by modeling their experimental adsorption isotherms using the Langmuir–Volmer model. All MIPs show similar adsorbent performance although the functional monomers were quite different and the interactions with fenamiphos were weak. The latter were assessed by 1H and 31P NMR experiments in DMSO‑d6 solution. The adsorption process presented weakly exothermic and endothermic behavior onto molecular imprints and non-specific sites respectively. The selectivity for adsorption of fenamiphos with respect to its sulfone and sulfoxide metabolites was quite high.

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hal-03806439 , version 1 (07-10-2022)

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Chaima Nasraoui, Najeh Jaoued-Grayaa, Laurent Vanoye, Yves Chevalier, Souhaira Hbaieb. Development of molecularly imprinted polymer for the selective recognition of the weakly interacting fenamiphos molecule. European Polymer Journal, 2022, 177, pp.111441. ⟨10.1016/j.eurpolymj.2022.111441⟩. ⟨hal-03806439⟩
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