Syntheses of new chiral chimeric photo-organocatalysts
Résumé
A new family of chiral chimeric photo-organocatalysts derived from phosphoric acid were synthesized and their spectroscopic and electrochemical properties were investigated. Then, the ability of these photoactivable molecules to catalyse an asymmetric tandem electrophilic b-amination of enecarbamates was evaluated.
Domaines
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Référence hal-03660600 Article Wei‐yang Ma, Emeric Montinho‐inacio, Bogdan Iorga, Pascal Retailleau, Xavier Moreau, et al.. Chiral Phosphoric Acid‐Catalyzed Enantioselective Formal [4+2] Cycloaddition Between Dienecarbamates and 2‐Benzothioazolimines. Advanced Synthesis and Catalysis, 2022, 364 (10), pp.1708-1715. ⟨10.1002/adsc.202200161⟩. ⟨hal-03660600⟩