A Cyclic Divalent N(I) Species Isoelectronic to Carbodiphosphoranes
Résumé
The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(I) salt. DFT study of this compound reveals the low valent character of the N(I) center.
Domaines
ChimieOrigine | Fichiers produits par l'(les) auteur(s) |
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