Visible-Light Photocatalysis Promoted by Solid-and Liquid-Phase Immobilized Transition Metal Complexes in Organic Synthesis
Résumé
This review summarizes synthetic approaches to reusable photocatalytic systems based on visible light-active transition metal complexes with chelating ligands containing pyridyl residues such as 2,2′-bipyridines, 1,10-phenanthrolines, 2,2′:6′,2′′-terpyridines and related ligands. The use of these materials in organic synthesis is then discussed focusing on 1) most active systems exhibiting a synergy effect between photophysical properties of immobilized complexes and photoactive solid supports and 2) the possibility of repeated uses of the developed catalytic system.
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