Distal Construction of a Carbon‐SCF 2 R Bond on Aliphatic Alcohols Enabled by 1,5‐Hydrogen‐Atom Transfer - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2022

Distal Construction of a Carbon‐SCF 2 R Bond on Aliphatic Alcohols Enabled by 1,5‐Hydrogen‐Atom Transfer

Résumé

An approach for the distal construction of a C(sp3)−SCF2R bond on aliphatic alcohols enabled by 1,5-hydrogen-atom transfer (HAT) was developed. In the presence of a hypervalent iodine (PIDA) and readily available ArSO2SCF2R reagents, this transition metal-free approach allowed the remote functionalization of a broad variety of alcohols with emergent and high added-value SCF2R moieties (R=H, F, CO2Et and PO(OEt)2) under blue light irradiation.
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hal-03744645 , version 1 (16-11-2022)

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Fabien Petit-Cancelier, Louise Ruyet, Samuel Couve-Bonnaire, Tatiana Besset. Distal Construction of a Carbon‐SCF 2 R Bond on Aliphatic Alcohols Enabled by 1,5‐Hydrogen‐Atom Transfer. Advanced Synthesis and Catalysis, 2022, 364 (8), pp.1498-1502. ⟨10.1002/adsc.202200059⟩. ⟨hal-03744645⟩
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