N‐Thiocyanato‐2,10‐camphorsultam Derivatives: Design and Applications of Original Electrophilic Thiocyanating Reagents
Résumé
The synthesis of bench-stable electrophilic thiocyanating reagents was depicted in two steps from readily available starting materials in good yields. These newly-designed electrophilic reagents were successfully applied for the thiocyanation of different nucleophiles under mild and transition
metal-free conditions. Preliminary experiments for the asymmetric C3-thiocyanation of an oxindole derivative were also conducted leading to the expected product with no induction of chirality, although opening possibilities for accessing chiral compounds.
Origine | Fichiers produits par l'(les) auteur(s) |
---|