Do ν(CO) Stretching Frequencies in Metal Carbonyl Complexes Unequivocally Correlate with the Intrinsic Electron-Donicity of Ancillary Ligands? - Archive ouverte HAL
Article Dans Une Revue Chemistry - A European Journal Année : 2011

Do ν(CO) Stretching Frequencies in Metal Carbonyl Complexes Unequivocally Correlate with the Intrinsic Electron-Donicity of Ancillary Ligands?

Résumé

Distorting the ν(CO) response: Weak Cipso⋅⋅⋅C≡O and Hortho⋅⋅⋅C≡O interligand interactions within MnI aryloxycarbene complexes are seen to induce a significant redshift of the corresponding IR ν(CO) stretching frequencies, revealing that the position of such bands may not unequivocally correlate with the intrinsic electron-donicity of ancillary ligands.

Dates et versions

hal-03739879 , version 1 (28-07-2022)

Identifiants

Citer

Dmitry A. Valyaev, Rémy Brousses, Noël Lugan, Israel Fernández, Miguel Sierra. Do ν(CO) Stretching Frequencies in Metal Carbonyl Complexes Unequivocally Correlate with the Intrinsic Electron-Donicity of Ancillary Ligands?. Chemistry - A European Journal, 2011, 17 (24), pp.6602-6605. ⟨10.1002/chem.201100651⟩. ⟨hal-03739879⟩
16 Consultations
0 Téléchargements

Altmetric

Partager

More