Synthesis and Rearrangement of Intramolecularly Stabilized 1.sigma.2,3.sigma.2-Diphosphaallylic Cations into Intramolecularly Stabilized 1.sigma.1,3.sigma.3-Diphosphaallylic Cations - Archive ouverte HAL
Article Dans Une Revue Journal of the American Chemical Society Année : 1994

Synthesis and Rearrangement of Intramolecularly Stabilized 1.sigma.2,3.sigma.2-Diphosphaallylic Cations into Intramolecularly Stabilized 1.sigma.1,3.sigma.3-Diphosphaallylic Cations

Résumé

Two equivalents of boron trifluoride-diethyl ether complex or 1 equiv of trifluoromethanesulfonic acid reacts with C-[bis(diisopropylamino)phosphino]-C,P-bis(diisopropylamino)phosphaalkene 1, cleaving one of the diisopropylamino substituents at the

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Chimie de coordination

Marie-Hélène Gulli  : Connectez-vous pour contacter le contributeur

https://hal.science/hal-03739862

Soumis le : jeudi 28 juillet 2022-13:49:08

Dernière modification le : jeudi 18 juillet 2024-10:51:31

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hal-03739862 , version 1 (28-07-2022)

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Michele Soleilhavoup, Yves Canac, Alexander Polozov, Antoine Baceiredo, Guy Bertrand. Synthesis and Rearrangement of Intramolecularly Stabilized 1.sigma.2,3.sigma.2-Diphosphaallylic Cations into Intramolecularly Stabilized 1.sigma.1,3.sigma.3-Diphosphaallylic Cations. Journal of the American Chemical Society, 1994, 116 (14), pp.6149-6152. ⟨10.1021/ja00093a012⟩. ⟨hal-03739862⟩

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