Synthesis of a Cationic 1,3-Diphospha-2,4-dipallada(II)tricyclo[1.1.1]pentane Derivative: The First Structurally Characterized Pyramidalμ2-Phosphinidene - Archive ouverte HAL
Article Dans Une Revue Angewandte Chemie International Edition Année : 1996

Synthesis of a Cationic 1,3-Diphospha-2,4-dipallada(II)tricyclo[1.1.1]pentane Derivative: The First Structurally Characterized Pyramidalμ2-Phosphinidene

Résumé

Two pyramidalized μ2-phosphinidene units are present in the cation 1 shown on the right. The complex 1-BFurn:x-wiley:05700833:media:ANIE199526771:tex2gif-stack-1, formed by heating a solution of a diphosphapalladacyclobutene in dichloromethane to reflux in the presence of a diphosphirenium salt, was characterized by an X-ray structure analysis.

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Chimie de coordination

Marie-Hélène Gulli  : Connectez-vous pour contacter le contributeur

https://hal.science/hal-03739855

Soumis le : jeudi 28 juillet 2022-13:35:57

Dernière modification le : jeudi 18 juillet 2024-10:52:58

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Dates et versions

hal-03739855 , version 1 (28-07-2022)

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Yves Canac, Antoine Baceiredo, Heinz Gornitzka, Dietmar Stalke, Guy Bertrand. Synthesis of a Cationic 1,3-Diphospha-2,4-dipallada(II)tricyclo[1.1.1]pentane Derivative: The First Structurally Characterized Pyramidalμ2-Phosphinidene. Angewandte Chemie International Edition, 1996, 34 (2324), pp.2677-2679. ⟨10.1002/anie.199526771⟩. ⟨hal-03739855⟩

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