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Article Dans Une Revue Phosphorus, Sulfur, and Silicon and the Related Elements Année : 1999

2-Π- and 3-Π-Electron Diphosphorus-Containing 3-Membered Heterocycles

Résumé

The heterolytic cleavage of the P-N bond of the coordinated 1H-diphosphirene 5 gives the corresponding diphosphirenylium complex 6, while the homolytic cleavage of the P-N bond of the free 1H-diphosphirene 4 affords the transient diphosphirenyl radical 7 and the ensuing stable dimer 8 which features original half P-P bonds.
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hal-03739779 , version 1 (28-07-2022)

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Yves Canac, Didier Bourissou, Heinz Gornitzka, Wolfgang Schoeller, Antoine Baceiredo, et al.. 2-Π- and 3-Π-Electron Diphosphorus-Containing 3-Membered Heterocycles. Phosphorus, Sulfur, and Silicon and the Related Elements, 1999, 144 (1), pp.37-40. ⟨10.1080/10426509908546176⟩. ⟨hal-03739779⟩
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