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Article Dans Une Revue Chemical Communications Année : 2021

Redox-induced reversible P-P coupling in a uranium complex

Résumé

A synthesized redox-active multidentate N-P ligand reacted with UCl4 in the presence of KHMDS or (BuLi)-Bu-n, where two novel U(iv) complexes with or without P-P coupling were formed, respectively. The reversible P-P coupling in these complexes was observed in redox-induced reactions.
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Dates et versions

hal-03717284 , version 1 (08-07-2022)

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Wei Fang, Ambre Carpentier, Xiong Sun, Yue Zhao, Laurent Maron, et al.. Redox-induced reversible P-P coupling in a uranium complex. Chemical Communications, 2021, 57 (91), pp.12175-12178. ⟨10.1039/d1cc04765e⟩. ⟨hal-03717284⟩
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