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Article Dans Une Revue Chemical Communications Année : 2021

A monoanionic pentadentate ligand platform for scandium-pnictogen multiple bonds

Résumé

A new monoanionic pentadentate ligand is designed to accommodate Sc = E bonds (E = N, P). The imido complex is stable enough to isolate and characterize, and reacts rapidly with CO2. The phosphinidene, on the other hand, is highly reactive and induces C-C bond cleavage to yield a phosphido-pyridyl complex which also undergoes rapid reacton with CO2.
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Dates et versions

hal-03717264 , version 1 (08-07-2022)

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Citer

Evan A. Patrick, Yan Yang, Warren E. Piers, Laurent Maron, Benjamin S. Gelfand. A monoanionic pentadentate ligand platform for scandium-pnictogen multiple bonds. Chemical Communications, 2021, 57 (69), pp.8640-8643. ⟨10.1039/d1cc03481b⟩. ⟨hal-03717264⟩
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