During the period from 17 March to 10 May 2020, France saw dramatic shifts in domestic, industrial and transport activities as a national lockdown was introduced. So far, studies have generally focused on urban settings, by contrast, this work reports data for a peri-urban location. Air samples were collected and analyzed using a fully automated GC-MS-FID system in an air quality monitoring station situated in the suburbs of Orléans, France. Average concentrations of BTEX (benzene, toluene, ethylbenzene, and xylenes) before, during, and after lockdown, were 402 ± 143, 800 ± 378 and 851 ± 445 pptv, respectively. Diurnal variation in BTEX and correlations between each of its components were analyzed to determine its various sources. The toluene/benzene (T/B) and m,p-xylene/ethylbenzene (MP/E) ratios, photochemical ages were used to explore whether the BTEX were from local or more distant sources. Together with a host of complementary measurements including NOx, O3, black carbon, meteorological parameters, and anthropogenic activities, we were able to make some inferences on the sources of BTEX. The results suggest that although anomalous local anthropogenic activity can lead to significant changes in BTEX concentrations, pollution levels in Orléans are mostly dependent on meteorological conditions, specifically whether the winds are coming from the Paris region. It appears, based on these measurements, that the pollution in the Orléans area is very much tied to the nearby megacity of Paris, this may be true for other peri-urban sites with implications for city planning and pollution mitigation strategies.