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Communication Dans Un Congrès Année : 2022

Accounting for multiple scattering effects for the evaluation of absorption and scattering cross sections

Résumé

Aerosols such as soot are a matter of concern in our daily life. Due to their impact on human health but also on global warming, their characterization is of extremely high relevance. In this context, extensive work has been done to characterize soot particles by optical techniques because such approaches enable an in-situ determination. These techniques essentially rely on the attenuation of the light (LOSA), on the scattering properties (Angular Light Scattering) or on their thermal behaviour after laser heating (LII). In any cases, the signals are interpreted based on models requiring precise light-particles theories in order to express the absorption and scattering cross sections. For nano-aerosols as soot, the Rayleigh-Debye-Gans (RDG) approximation for fractal aggregates (FA) is frequently used essentially due to its simplicity since it provides a simple analytical expression of the scattering and absorption cross sections. However, this approximation relies on two strong assumptions. First, the monomers composing the aggregate behave as Rayleigh spheres, i.e., they are small enough compared to the wavelength and transparent enough to make the phase shift negligible. Second, it is supposed that there is no electromagnetic coupling between the monomers (internal multiple-scattering), i.e., each one sees only the incident light and not the light scattered by its neighbours. Many studies have compared rigorous solutions with RDG-FA ones and observed important discrepancies. Indeed, RDG-FA can lead to errors up to 45% on the predicted forward scattering [1, 2] and optical determination of the fractal dimension can be overestimated by a factor up to 10% [3]. Also, impact on LII measurements has been shown to be potentially important [4]. Nevertheless, the precise underlying mechanisms leading to these discrepancies were not well understood and thus, until now, no models where proposed to improve RDG-FA theory regarding the internal coupling effects.The present communication aims to show to the LII and soot communities the recent advances made on this topic which were achieved by the use of the phasor approach which enables a comprehensive description of the internal electric field and its link with corrections to bring to RDGFA. The internal coupling effects will be first illustrated for a pair of monomers [5] followed by fractal aggregates [6]. Correction factors will be proposed for absorption and forward scattering. Recent advances concerning the impact of internal coupling on scattering structure factor will be also presented.
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Dates et versions

hal-03695850 , version 1 (15-06-2022)

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  • HAL Id : hal-03695850 , version 1

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Clément Argentin, Marek Mazur, Romain Ceolato, Matthew J. Berg, Yon Jérôme. Accounting for multiple scattering effects for the evaluation of absorption and scattering cross sections. LII Workshop, Jun 2022, Glasgow, United Kingdom. ⟨hal-03695850⟩
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