<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-03695710</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-17T04:06:37+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Thermally Conductive and Leakage-Proof Phase-Change Materials Composed of Dense Graphene Foam and Paraffin for Thermal Management</title>
            <author role="aut">
              <persName>
                <forename type="first">Hongling</forename>
                <surname>Li</surname>
              </persName>
              <idno type="idhal" notation="numeric">816331</idno>
              <idno type="halauthorid" notation="string">2351006-816331</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-2292-1949</idno>
              <affiliation ref="#struct-300732"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Roland Yingjie</forename>
                <surname>Tay</surname>
              </persName>
              <idno type="halauthorid">2524206-0</idno>
              <affiliation ref="#struct-300732"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Siu Hon</forename>
                <surname>Tsang</surname>
              </persName>
              <idno type="halauthorid">1740762-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Romain</forename>
                <surname>Hubert</surname>
              </persName>
              <idno type="idhal" notation="numeric">816329</idno>
              <idno type="halauthorid" notation="string">2351004-816329</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-3188-2002</idno>
              <affiliation ref="#struct-1066983"/>
              <affiliation ref="#struct-254061"/>
              <affiliation ref="#struct-27438"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Philippe</forename>
                <surname>Coquet</surname>
              </persName>
              <email type="md5">657a739e67a791d7f7b62c1957721afd</email>
              <email type="domain">iemn.univ-lille1.fr</email>
              <idno type="idhal" notation="string">philippe-coquet</idno>
              <idno type="idhal" notation="numeric">747455</idno>
              <idno type="halauthorid" notation="string">658874-747455</idno>
              <affiliation ref="#struct-1066983"/>
              <affiliation ref="#struct-254061"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Thomas</forename>
                <surname>Merlet</surname>
              </persName>
              <email type="md5">3192e8a717d1c0242a277d5a36087bbe</email>
              <email type="domain">thalesgroup.com</email>
              <idno type="idhal" notation="numeric">920375</idno>
              <idno type="halauthorid" notation="string">616234-920375</idno>
              <affiliation ref="#struct-530280"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Jerome</forename>
                <surname>Foncin</surname>
              </persName>
              <idno type="idhal" notation="numeric">816330</idno>
              <idno type="halauthorid" notation="string">2351005-816330</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-0223-8640</idno>
              <affiliation ref="#struct-185003"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Jong Jen</forename>
                <surname>Yu</surname>
              </persName>
              <idno type="halauthorid">2524207-0</idno>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Edwin Hang Tong</forename>
                <surname>Teo</surname>
              </persName>
              <idno type="halauthorid">626430-0</idno>
              <affiliation ref="#struct-254061"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Collection</forename>
                <surname>IEMN</surname>
              </persName>
              <email type="md5">f3c4c8abd4ffdc9885dbd6e4ca535087</email>
              <email type="domain">iemn.fr</email>
            </editor>
            <funder>The authors would like to acknowledge the financial support from Thales.</funder>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2022-06-15 10:00:40</date>
              <date type="whenModified">2026-03-23 09:10:02</date>
              <date type="whenReleased">2022-06-15 10:00:40</date>
              <date type="whenProduced">2022-06-24</date>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="102579">
                <persName>
                  <forename>Collection</forename>
                  <surname>IEMN</surname>
                </persName>
                <email type="md5">f3c4c8abd4ffdc9885dbd6e4ca535087</email>
                <email type="domain">iemn.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-03695710</idno>
            <idno type="halUri">https://hal.science/hal-03695710</idno>
            <idno type="halBibtex">li:hal-03695710</idno>
            <idno type="halRefHtml">&lt;i&gt;ACS Applied Nano Materials&lt;/i&gt;, 2022, 5 (6), pp.8362-8370. &lt;a target="_blank" href="https://dx.doi.org/10.1021/acsanm.2c01462"&gt;&amp;#x27E8;10.1021/acsanm.2c01462&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">ACS Applied Nano Materials, 2022, 5 (6), pp.8362-8370. &amp;#x27E8;10.1021/acsanm.2c01462&amp;#x27E9;</idno>
            <availability status="restricted"/>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-VALENCIENNES">Université de Valenciennes et du Hainaut-Cambresis</idno>
            <idno type="stamp" n="IEMN">Institut d'électronique, de microélectronique et de nanotechnologie</idno>
            <idno type="stamp" n="UNIV-LILLE">Université de Lille</idno>
            <idno type="stamp" n="UNIV-CATHOLILLE">Université catholique de Lille</idno>
            <idno type="stamp" n="TEST-UPHF">TEST-UPHF</idno>
            <idno type="stamp" n="CINTRA">Advancing Materials Research through France–Singapore Collaboration</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Thermally Conductive and Leakage-Proof Phase-Change Materials Composed of Dense Graphene Foam and Paraffin for Thermal Management</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Hongling</forename>
                    <surname>Li</surname>
                  </persName>
                  <idno type="idhal" notation="numeric">816331</idno>
                  <idno type="halauthorid" notation="string">2351006-816331</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-2292-1949</idno>
                  <affiliation ref="#struct-300732"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Roland Yingjie</forename>
                    <surname>Tay</surname>
                  </persName>
                  <idno type="halauthorid">2524206-0</idno>
                  <affiliation ref="#struct-300732"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Siu Hon</forename>
                    <surname>Tsang</surname>
                  </persName>
                  <idno type="halauthorid">1740762-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Romain</forename>
                    <surname>Hubert</surname>
                  </persName>
                  <idno type="idhal" notation="numeric">816329</idno>
                  <idno type="halauthorid" notation="string">2351004-816329</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-3188-2002</idno>
                  <affiliation ref="#struct-1066983"/>
                  <affiliation ref="#struct-254061"/>
                  <affiliation ref="#struct-27438"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Philippe</forename>
                    <surname>Coquet</surname>
                  </persName>
                  <email type="md5">657a739e67a791d7f7b62c1957721afd</email>
                  <email type="domain">iemn.univ-lille1.fr</email>
                  <idno type="idhal" notation="string">philippe-coquet</idno>
                  <idno type="idhal" notation="numeric">747455</idno>
                  <idno type="halauthorid" notation="string">658874-747455</idno>
                  <affiliation ref="#struct-1066983"/>
                  <affiliation ref="#struct-254061"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Thomas</forename>
                    <surname>Merlet</surname>
                  </persName>
                  <email type="md5">3192e8a717d1c0242a277d5a36087bbe</email>
                  <email type="domain">thalesgroup.com</email>
                  <idno type="idhal" notation="numeric">920375</idno>
                  <idno type="halauthorid" notation="string">616234-920375</idno>
                  <affiliation ref="#struct-530280"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Jerome</forename>
                    <surname>Foncin</surname>
                  </persName>
                  <idno type="idhal" notation="numeric">816330</idno>
                  <idno type="halauthorid" notation="string">2351005-816330</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-0223-8640</idno>
                  <affiliation ref="#struct-185003"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Jong Jen</forename>
                    <surname>Yu</surname>
                  </persName>
                  <idno type="halauthorid">2524207-0</idno>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Edwin Hang Tong</forename>
                    <surname>Teo</surname>
                  </persName>
                  <idno type="halauthorid">626430-0</idno>
                  <affiliation ref="#struct-254061"/>
                </author>
              </analytic>
              <monogr>
                <idno type="localRef">flagship_materials</idno>
                <idno type="halJournalId" status="VALID">123939</idno>
                <idno type="issn">2574-0970</idno>
                <title level="j">ACS Applied Nano Materials</title>
                <imprint>
                  <publisher>American Chemical Society</publisher>
                  <biblScope unit="volume">5</biblScope>
                  <biblScope unit="issue">6</biblScope>
                  <biblScope unit="pp">8362–8370</biblScope>
                  <date type="datePub">2022-06-24</date>
                  <date type="dateEpub">2022-06-08</date>
                </imprint>
              </monogr>
              <idno type="doi">10.1021/acsanm.2c01462</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">thermal management</term>
                <term xml:lang="en">thermal conductivity</term>
                <term xml:lang="en">latent heat</term>
                <term xml:lang="en">dense graphene foam</term>
                <term xml:lang="en">composite phase-change material</term>
              </keywords>
              <classCode scheme="halDomain" n="spi">Engineering Sciences [physics]</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Practical implementation of porous carbon-based composite phase-change materials (CPCMs) for heat dissipation in high-power-density electronics is usually limited by liquid leakage issues and unsatisfactory thermal conductivity resulting from their relatively low filler fraction and/or existence of interfacial thermal resistance between fillers. Therefore, development of shape-stable CPCMs with high thermal conductivity and large latent heat to avoid overheating of electronics remains challenging. Herein, graphene foams (GFs) with very high densities of up to 204 mg/cm3 have been synthesized to act as interconnected porous networks of CPCMs. Notably, the obtained CPCM with a filler loading of 11.1 wt % preserves a high heat capacity (171.8 J/g) with a retention of 84.8% while showing a 22.6-fold enhancement in the thermal conductivity as compared to pure PCM (10.13 vs 0.43 W/m·K). A higher thermal conductivity of 14.29 W/m·K can be achieved by further increasing the filler loading to 17.7 wt %, which outperforms many of the previously reported CPCMs based on the interconnected porous carbon-based frameworks. Owing to the superior interconnected network structure of the dense GFs and the strong interconnection between them and PCM molecules, these CPCMs also exhibit leakage-proof shape stability and excellent thermal reliability (at least 100 cycles). Moreover, a state-of-the-art aluminum (Al) package based on the CPCM (filler loading: 11.1 wt %) possessing weight 60% less than its pure Al panel counterpart has been demonstrated to verify better heat transfer efficiency and more efficient phonon pathways of the CPCM composite than those of the pure PCM, which holds great promise for advanced thermal management of emerging applications in electronics.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="institution" xml:id="struct-300732" status="VALID">
          <idno type="ROR">https://ror.org/02e7b5302</idno>
          <orgName>Nanyang Technological University [Singapour]</orgName>
          <orgName type="acronym">NTU</orgName>
          <date type="start">1955-01-01</date>
          <desc>
            <address>
              <addrLine>50 Nanyang Avenue, Singapour 639798</addrLine>
              <country key="SG"/>
            </address>
            <ref type="url">https://www.ntu.edu.sg/</ref>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-1066983" status="VALID">
          <idno type="IdRef">138736421</idno>
          <idno type="ISNI">0000000403683863</idno>
          <idno type="RNSR">199812849E</idno>
          <idno type="ROR">https://ror.org/02q4res37</idno>
          <idno type="Wikidata">Q3151942</idno>
          <orgName>Institut d’Électronique, de Microélectronique et de Nanotechnologie - UMR 8520</orgName>
          <orgName type="acronym">IEMN</orgName>
          <date type="start">2021-01-01</date>
          <desc>
            <address>
              <addrLine>[Univ. Lille, CNRS, Centrale Lille Institut, Junia, Univ. Polytechnique Hauts-de-France] ––Laboratoire Central – Cité Scientifique – Avenue Poincaré – CS 60069 – 59652 VILLENEUVE D’ASCQ CEDEX</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.iemn.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-120930" type="direct"/>
            <relation active="#struct-374570" type="direct"/>
            <relation name="UMR8520" active="#struct-441569" type="direct"/>
            <relation active="#struct-1001263" type="direct"/>
            <relation active="#struct-1059196" type="direct"/>
            <relation active="#struct-300877" type="indirect"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-254061" status="VALID">
          <idno type="RNSR">200919745C</idno>
          <orgName>CNRS International - NTU - Thales Research Alliance</orgName>
          <orgName type="acronym">CINTRA</orgName>
          <date type="start">2009-01-01</date>
          <desc>
            <address>
              <addrLine>Research Techno Plaza, 50 Nanyang Drive, Singapore 637553</addrLine>
              <country key="SG"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-250969" type="direct"/>
            <relation active="#struct-300732" type="direct"/>
            <relation name="IRL3288 / UMI3288" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-27438" status="VALID">
          <orgName>THALES Airborne Systems [Elancourt]</orgName>
          <desc>
            <address>
              <addrLine>1 Bd Jean Moulin 78852 Elancourt</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://sma.lip6.fr/Csma/equipes/thales.htm</ref>
          </desc>
          <listRelation>
            <relation active="#struct-250969" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-530280" status="VALID">
          <orgName>Thales LAS France</orgName>
          <date type="start">2018-01-01</date>
          <desc>
            <address>
              <addrLine>2 AV GAY LUSSAC, 78990 ELANCOURT</addrLine>
              <country key="FR"/>
            </address>
          </desc>
        </org>
        <org type="laboratory" xml:id="struct-185003" status="VALID">
          <orgName>Thales Air Systems</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-250969" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-120930" status="VALID">
          <idno type="IdRef">256304629</idno>
          <idno type="ISNI">0000000122034461</idno>
          <idno type="ROR">https://ror.org/01x441g73</idno>
          <orgName>Centrale Lille</orgName>
          <desc>
            <address>
              <addrLine>École Centrale de Lille - Cité Scientifique - CS 20048 59651 Villeneuve d'Ascq Cedex</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://centralelille.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-374570" status="VALID">
          <idno type="IdRef">223446556</idno>
          <idno type="ISNI">0000 0001 2242 6780</idno>
          <idno type="ROR">https://ror.org/02kzqn938</idno>
          <idno type="Wikidata">Q3551621</idno>
          <orgName>Université de Lille</orgName>
          <desc>
            <address>
              <addrLine>EPE Université de Lille. -- 42 rue Paul Duez, 59000 Lille</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-lille.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-1001263" status="VALID">
          <idno type="IdRef">242335675</idno>
          <idno type="ROR">https://ror.org/02ezch769</idno>
          <orgName>Université Polytechnique Hauts-de-France</orgName>
          <orgName type="acronym">UPHF</orgName>
          <date type="start">2019-09-09</date>
          <desc>
            <address>
              <addrLine>Campus Mont Houy59313 Valenciennes Cedex 9</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.uphf.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-1059196" status="VALID">
          <idno type="IdRef">258598026</idno>
          <idno type="ROR">https://ror.org/02evec030</idno>
          <orgName>JUNIA</orgName>
          <orgName type="acronym">JUNIA</orgName>
          <date type="start">2021-01-01</date>
          <desc>
            <address>
              <addrLine>2 Rue Norbert Segard59014 Lille</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.junia.com/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-300877" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-300877" status="VALID">
          <idno type="IdRef">026582481</idno>
          <idno type="ROR">https://ror.org/025s1b152</idno>
          <orgName>Université catholique de Lille</orgName>
          <orgName type="acronym">UCL</orgName>
          <desc>
            <address>
              <addrLine>60 boulevard Vauban - 59800 Lille</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-catholille.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-250969" status="VALID">
          <orgName>THALES [France]</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.thalesgroup.com/fr/europe/france</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>