A Linear Metal-Metal Bonded Tri-Iron Single-Molecule Magnet
Résumé
The linear trinuclear complex cation [Fe 3 (DpyF) 4 ] 2+ was prepared as [Fe 3 (DpyF) 4 ](BF 4) 2 . 2CH 3 CN. With large Fe-Fe distances of 2.78 Å, this complex demonstrates intramolecular ferromagnetic coupling between the anisotropic Fe II centers (J/k B = +20.9(5) K) giving an S T = 6 ground state and exhibits single-molecule magnet properties.
Domaines
Matériaux| Origine | Fichiers produits par l'(les) auteur(s) |
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