Room-Temperature Doping of CsPbBr3 Nanocrystals with Aluminum
Résumé
B-site doping is an emerging strategy for tuning the emission wavelength of cesium lead
halide ABX3 nanocrystals. We present a simple method for the post-synthetic doping of CsPbBr3
nanocrystals with aluminum at room temperature by exposing them to a solution of AlBr3 in
dibromomethane. Despite the much smaller ionic radius of Al3+ compared to Pb2+, nominal doping
levels in a range from 8.1% to 24.3% were obtained when increasing the Al/Pb feed ratio from 1 to 4.5.
Al3+ introduction leads to a hypsochromic shift of the photoluminescence (PL) emission of the CsPbBr3
nanocrystals. The PL peak position is highly stable over at least 6 months and tunable in a range of 510
to 480 nm by increasing the doping level. Structural analyses revealed a linear correlation between the
PL energy and the lattice parameter with a slope of -1.96 eV/Å.
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