μ 3 -Carbonato-κ 3 O : O ′: O ′′-tris{(η 6 -benzene)[( R )-1-(1-aminoethyl)naphthyl-κ 2 C 2 , N ]ruthenium(II)} hexafluoridophosphate dichloromethane solvate - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Acta Crystallographica Section E : Structure Reports Online [2001-2014] Année : 2008

μ 3 -Carbonato-κ 3 O : O ′: O ′′-tris{(η 6 -benzene)[( R )-1-(1-aminoethyl)naphthyl-κ 2 C 2 , N ]ruthenium(II)} hexafluoridophosphate dichloromethane solvate

Résumé

The title compound, [Ru3(C12H12N)3(CO3)(C6H6)3]PF6·CH2Cl2, was obtained unintentionally as the product of an attempted deprotonation of the monomeric parent ruthenium complex [Ru(C12H12N)(C6H6)(C2H3N)]PF6. The carbonate ligand bridges three half-sandwich cyclo­ruthenated fragments, each of them exhibiting a pseudo-tetra­hedral geometry. The configuration of the Ru atoms is S. The naphthyl groups of the enanti­opure cyclo­ruthenated benzylic amine ligands point in the same direction, adopting a propeller shape.

Dates et versions

hal-03639751 , version 1 (13-04-2022)

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Citer

Jean-Baptiste Sortais, Lydia Brelot, Michel Pfeffer, Laurent Barloy. μ 3 -Carbonato-κ 3 O : O ′: O ′′-tris{(η 6 -benzene)[( R )-1-(1-aminoethyl)naphthyl-κ 2 C 2 , N ]ruthenium(II)} hexafluoridophosphate dichloromethane solvate. Acta Crystallographica Section E : Structure Reports Online [2001-2014], 2008, 64 (3), pp.m483-m484. ⟨10.1107/S1600536808003978⟩. ⟨hal-03639751⟩

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