Cycling stability of a hybrid activated carbon//poly(3-methylthiophene) supercapacitor with N-butyl-Nmethylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquid as electrolyte - Archive ouverte HAL Access content directly
Journal Articles Electrochimica Acta Year : 2005

Cycling stability of a hybrid activated carbon//poly(3-methylthiophene) supercapacitor with N-butyl-Nmethylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquid as electrolyte

Abstract

A long cycle-life, high-voltage supercapacitor featuring an activated carbon//poly(3-methylthiophene) hybrid configuration with N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquid, a solvent-free green electrolyte, was developed. The cyclability of a laboratory scale cell with electrode mass loading sized for practical uses was tested at 60 °C over 16,000 galvanostatic charge–discharge cycles at 10 mA cm−2 in the 1.5 and 3.6 V voltage range. The reported average and maximum specific energy and power, specific capacitance and capacity, equivalent series resistance and coulombic efficiency over cycling demonstrate the long-term viability of this ionic liquid as green electrolyte for high-voltage hybrid supercapacitors.
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hal-03601475 , version 1 (08-03-2022)

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Andrea Balducci, Wesley Henderson, Marina Mastragostino, Stefano Passerini, Patrice Simon, et al.. Cycling stability of a hybrid activated carbon//poly(3-methylthiophene) supercapacitor with N-butyl-Nmethylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquid as electrolyte. Electrochimica Acta, 2005, 5 (11), pp.2233-2237. ⟨10.1016/j.electacta.2004.10.006⟩. ⟨hal-03601475⟩
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