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Article Dans Une Revue Applied Catalysis A : General Année : 2006

Nanosized iron and iron–cobalt spinel oxides as catalysts for methanol decomposition

Résumé

Nanosized iron and mixed iron–cobalt oxides supported on activated carbon materials and their bulk analogues prepared by thermal synthesis are studied by X-rays diffraction, Mo¨ssbauer spectroscopy, magnetic measurements and temperature programmed reduction. Their catalytic behavior in methanol decomposition to H2, CO and methane is tested. Phase transformations in the metal oxides affected by the reaction medium are also investigated. Changes in the reaction mechanism of the methanol decomposition after the metal oxides deposition on the support as compared to the bulk phases are discussed.
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hal-03597065 , version 1 (04-03-2022)

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Elina Manova, Tanya Tsoncheva, Claude Estournès, Daniela Paneva, Krassimir Tenchev, et al.. Nanosized iron and iron–cobalt spinel oxides as catalysts for methanol decomposition. Applied Catalysis A : General, 2006, 300 (2), pp.170-180. ⟨10.1016/j.apcata.2005.11.005⟩. ⟨hal-03597065⟩
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