<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-03583421</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-13T03:32:00+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">Chamber study of the Oxalyl Chloride Photodissociation in Sunlight</title>
            <author role="crp">
              <persName>
                <forename type="first">Alexandre</forename>
                <surname>Kukui</surname>
              </persName>
              <email type="md5">6fe35cf914b3e459991ca52de1377cab</email>
              <email type="domain">cnrs-orleans.fr</email>
              <idno type="idhal" notation="string">alexandre-kukui</idno>
              <idno type="idhal" notation="numeric">735491</idno>
              <idno type="halauthorid" notation="string">30292-735491</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-3657-0414</idno>
              <idno type="IDREF">https://www.idref.fr/253133785</idno>
              <affiliation ref="#struct-185533"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Yangang</forename>
                <surname>Ren</surname>
              </persName>
              <email type="md5">4f21c498adc543077a2378aee1da676c</email>
              <email type="domain">cnrs-orleans.fr</email>
              <idno type="idhal" notation="numeric">783909</idno>
              <idno type="halauthorid" notation="string">2543096-783909</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-5770-5050</idno>
              <affiliation ref="#struct-474628"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Valéry</forename>
                <surname>Catoire</surname>
              </persName>
              <email type="md5">dc3435750069568b9996b70708e8b6b1</email>
              <email type="domain">cnrs-orleans.fr</email>
              <idno type="idhal" notation="string">valery-catoire</idno>
              <idno type="idhal" notation="numeric">185143</idno>
              <idno type="halauthorid" notation="string">19429-185143</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/E-9662-2015</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-8126-3096</idno>
              <idno type="IDREF">https://www.idref.fr/148082920</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/E-9662-2015</idno>
              <affiliation ref="#struct-185533"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Véronique</forename>
                <surname>Daële</surname>
              </persName>
              <email type="md5">b94b29e0027360f3535bdb27ab016863</email>
              <email type="domain">cnrs-orleans.fr</email>
              <idno type="idhal" notation="string">veronique-daele</idno>
              <idno type="idhal" notation="numeric">175159</idno>
              <idno type="halauthorid" notation="string">14541-175159</idno>
              <idno type="ORCID">https://orcid.org/0000-0003-2509-4077</idno>
              <idno type="IDREF">https://www.idref.fr/183874854</idno>
              <affiliation ref="#struct-474628"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Wahid</forename>
                <surname>Mellouki</surname>
              </persName>
              <email type="md5">7bf84baf3d1047633a5b9a16a8c4581c</email>
              <email type="domain">cnrs-orleans.fr</email>
              <idno type="idhal" notation="string">abdelwahid-mellouki</idno>
              <idno type="idhal" notation="numeric">181905</idno>
              <idno type="halauthorid" notation="string">30227-181905</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/H-5219-2011</idno>
              <idno type="ORCID">https://orcid.org/0000-0002-6594-5262</idno>
              <idno type="IDREF">https://www.idref.fr/069655197</idno>
              <affiliation ref="#struct-474628"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">A. R.</forename>
                <surname>Ravishankara</surname>
              </persName>
              <idno type="halauthorid">323822-0</idno>
              <affiliation ref="#struct-97463"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Veronique</forename>
                <surname>Daele</surname>
              </persName>
              <email type="md5">b94b29e0027360f3535bdb27ab016863</email>
              <email type="domain">cnrs-orleans.fr</email>
            </editor>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2022-03-04 16:28:22</date>
              <date type="whenModified">2025-06-04 03:26:19</date>
              <date type="whenReleased">2022-03-04 16:43:02</date>
              <date type="whenProduced">2019-06-23</date>
              <date type="whenEndEmbargoed">2022-03-04</date>
              <ref type="file" target="https://hal.science/hal-03583421v1/document">
                <date notBefore="2022-03-04"/>
              </ref>
              <ref type="file" subtype="author" n="1" target="https://hal.science/hal-03583421v1/file/ICCK2019.pdf" id="file-3583421-3146335">
                <date notBefore="2022-03-04"/>
              </ref>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="46826">
                <persName>
                  <forename>Veronique</forename>
                  <surname>Daele</surname>
                </persName>
                <email type="md5">b94b29e0027360f3535bdb27ab016863</email>
                <email type="domain">cnrs-orleans.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-03583421</idno>
            <idno type="halUri">https://hal.science/hal-03583421</idno>
            <idno type="halBibtex">kukui:hal-03583421</idno>
            <idno type="halRefHtml">&lt;i&gt;11th international Conference on Chemical kinetics (ICCK2019)&lt;/i&gt;, Jun 2019, Orléans, France. &lt;a target="_blank" href="https://icck2019.sciencesconf.org/"&gt;&lt;/a&gt;</idno>
            <idno type="halRef">11th international Conference on Chemical kinetics (ICCK2019), Jun 2019, Orléans, France. </idno>
            <availability status="restricted">
              <licence target="https://about.hal.science/hal-authorisation-v1/">HAL Authorization<ref corresp="#file-3583421-3146335"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="INSU">INSU - Institut National des Sciences de l'Univers</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="UNIV-ORLEANS">Université d'Orléans</idno>
            <idno type="stamp" n="CNES">CNES - Centre national d'études spatiales</idno>
            <idno type="stamp" n="OSUC" corresp="INSU">Observatoire des Sciences de l'Univers en région Centre</idno>
            <idno type="stamp" n="LPC2E" corresp="OSUC">Laboratoire de Physique et Chimie de l'Environnement et de l'Espace</idno>
            <idno type="stamp" n="CNRS_ICARE" corresp="UNIV-ORLEANS">Institut de Combustion Aérothermique Réactivité et Environnement</idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="invited" n="0">No</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
            <note type="proceedings" n="0">No</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">Chamber study of the Oxalyl Chloride Photodissociation in Sunlight</title>
                <author role="crp">
                  <persName>
                    <forename type="first">Alexandre</forename>
                    <surname>Kukui</surname>
                  </persName>
                  <email type="md5">6fe35cf914b3e459991ca52de1377cab</email>
                  <email type="domain">cnrs-orleans.fr</email>
                  <idno type="idhal" notation="string">alexandre-kukui</idno>
                  <idno type="idhal" notation="numeric">735491</idno>
                  <idno type="halauthorid" notation="string">30292-735491</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-3657-0414</idno>
                  <idno type="IDREF">https://www.idref.fr/253133785</idno>
                  <affiliation ref="#struct-185533"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Yangang</forename>
                    <surname>Ren</surname>
                  </persName>
                  <email type="md5">4f21c498adc543077a2378aee1da676c</email>
                  <email type="domain">cnrs-orleans.fr</email>
                  <idno type="idhal" notation="numeric">783909</idno>
                  <idno type="halauthorid" notation="string">2543096-783909</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-5770-5050</idno>
                  <affiliation ref="#struct-474628"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Valéry</forename>
                    <surname>Catoire</surname>
                  </persName>
                  <email type="md5">dc3435750069568b9996b70708e8b6b1</email>
                  <email type="domain">cnrs-orleans.fr</email>
                  <idno type="idhal" notation="string">valery-catoire</idno>
                  <idno type="idhal" notation="numeric">185143</idno>
                  <idno type="halauthorid" notation="string">19429-185143</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/E-9662-2015</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-8126-3096</idno>
                  <idno type="IDREF">https://www.idref.fr/148082920</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/E-9662-2015</idno>
                  <affiliation ref="#struct-185533"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Véronique</forename>
                    <surname>Daële</surname>
                  </persName>
                  <email type="md5">b94b29e0027360f3535bdb27ab016863</email>
                  <email type="domain">cnrs-orleans.fr</email>
                  <idno type="idhal" notation="string">veronique-daele</idno>
                  <idno type="idhal" notation="numeric">175159</idno>
                  <idno type="halauthorid" notation="string">14541-175159</idno>
                  <idno type="ORCID">https://orcid.org/0000-0003-2509-4077</idno>
                  <idno type="IDREF">https://www.idref.fr/183874854</idno>
                  <affiliation ref="#struct-474628"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Wahid</forename>
                    <surname>Mellouki</surname>
                  </persName>
                  <email type="md5">7bf84baf3d1047633a5b9a16a8c4581c</email>
                  <email type="domain">cnrs-orleans.fr</email>
                  <idno type="idhal" notation="string">abdelwahid-mellouki</idno>
                  <idno type="idhal" notation="numeric">181905</idno>
                  <idno type="halauthorid" notation="string">30227-181905</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/H-5219-2011</idno>
                  <idno type="ORCID">https://orcid.org/0000-0002-6594-5262</idno>
                  <idno type="IDREF">https://www.idref.fr/069655197</idno>
                  <affiliation ref="#struct-474628"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">A. R.</forename>
                    <surname>Ravishankara</surname>
                  </persName>
                  <idno type="halauthorid">323822-0</idno>
                  <affiliation ref="#struct-97463"/>
                </author>
              </analytic>
              <monogr>
                <meeting>
                  <title>11th international Conference on Chemical kinetics (ICCK2019)</title>
                  <date type="start">2019-06-23</date>
                  <date type="end">2019-06-27</date>
                  <settlement>Orléans</settlement>
                  <country key="FR">France</country>
                </meeting>
                <imprint/>
              </monogr>
              <ref type="publisher">https://icck2019.sciencesconf.org/</ref>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Photolysis</term>
                <term xml:lang="en">Oxalyl Chloride</term>
                <term xml:lang="en">Chamber</term>
                <term xml:lang="en">Kinetics</term>
                <term xml:lang="en">Peroxy Radicals</term>
                <term xml:lang="en">CIMS</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.theo">Chemical Sciences/Theoretical and/or physical chemistry</classCode>
              <classCode scheme="halTypology" n="POSTER">Poster communications</classCode>
              <classCode scheme="halOldTypology" n="POSTER">Poster communications</classCode>
              <classCode scheme="halTreeTypology" n="POSTER">Poster communications</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>Oxalyl chloride, (ClCO)2, has been used as a photolytic Cl atoms precursor for kinetic and photochemical studies. Previous studies of the (ClCO)2 photodynamic at 193, 248, and 351 nm suggest that UV photodissociation proceeds via a two-step mechanism including formation of an excited ClCO* radical (1) and dissociation of a fraction of the ClCO* depending on the photolysis wavelength into Cl + CO (2):(ClCO)2 + hv → ClCO* + CO + Cl (1)ClCO*→ Cl + CO (2)The ClCO radical formed with the energy lower than its dissociation barrier has been found to undergo unimolecular dissociation (3) on the time scale of several microseconds at room temperature and atmospheric pressure: ClCO + M → Cl + CO + M (3)In this work the photodissociation of (COCl)2 by solar irradiation has been studied in the HELIOS environmental chamber. An effective (COCl)2 dissociation quantum yield of 0.34±0.03 has been derived from the measured actinic flux in the chamber and the observed (COCl)2 decay rate. Thisresult is in agreement with previous studies. The relative yields of CO and Cl atoms were derived by comparing the (COCl)2 loss rate with the production rates of CO and Cl atoms. The Cl production rate was derived from the measured by CIMS steady state HO2 or CH3O2 radicalconcentrations generated by scavenging of Cl by H2 or CH4, respectively. The obtained relative CO yield of 2.2±0.1 is in agreement with previous studies. The relative yield of Cl has been found to be 2 times lower, 1.01±0.03, in disagreement with previous studies and suggesting anothermechanism of the (COCl)2 photodissociation at wavelengths longer than 300 nm.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-185533" status="VALID">
          <idno type="IdRef">167915916</idno>
          <idno type="ISNI">0000000406235273</idno>
          <idno type="RNSR">201220223J</idno>
          <idno type="ROR">https://ror.org/049k66y27</idno>
          <idno type="Wikidata">Q15967014</idno>
          <orgName>Laboratoire de Physique et Chimie de l'Environnement et de l'Espace</orgName>
          <orgName type="acronym">LPC2E</orgName>
          <date type="start">2012-01-01</date>
          <desc>
            <address>
              <addrLine>3A, Avenue de la Recherche Scientifique 45071 Orléans cedex 2</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.lpc2e.cnrs.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UMR7328" active="#struct-300045" type="direct"/>
            <relation active="#struct-300297" type="direct"/>
            <relation name="UMR7328" active="#struct-441569" type="direct"/>
            <relation name="UMR7328" active="#struct-458369" type="direct"/>
          </listRelation>
        </org>
        <org type="laboratory" xml:id="struct-474628" status="VALID">
          <idno type="IdRef">130578657</idno>
          <idno type="ISNI">0000000092583805</idno>
          <idno type="RNSR">200817616T</idno>
          <idno type="ROR">https://ror.org/03txr3336</idno>
          <idno type="Wikidata">Q30261464</idno>
          <orgName>Institut de Combustion, Aérothermique, Réactivité et Environnement</orgName>
          <orgName type="acronym">ICARE</orgName>
          <date type="start">2007-01-01</date>
          <desc>
            <address>
              <addrLine>1C, avenue de la Recherche Scientifique, CS 50060, 45071 - Orléans Cedex 2</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://icare.cnrs.fr/</ref>
          </desc>
          <listRelation>
            <relation name="UPR 3021" active="#struct-300297" type="direct"/>
            <relation name="UPR3021" active="#struct-441569" type="direct"/>
            <relation name="UPR3021" active="#struct-474627" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-97463" status="VALID">
          <idno type="ROR">https://ror.org/03k1gpj17</idno>
          <orgName>Colorado State University [Fort Collins]</orgName>
          <orgName type="acronym">CSU</orgName>
          <desc>
            <address>
              <addrLine>Colorado State University, Fort Collins, Colorado 80523 USA</addrLine>
              <country key="US"/>
            </address>
            <ref type="url">http://www.colostate.edu/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300045" status="VALID">
          <idno type="IdRef">029349265</idno>
          <idno type="ISNI">0000 0001 2154 1736</idno>
          <idno type="ROR">https://ror.org/04kdfz702</idno>
          <idno type="Wikidata">Q3152437</idno>
          <orgName>Institut national des sciences de l'Univers</orgName>
          <orgName type="acronym">INSU - CNRS</orgName>
          <date type="start">2007-04-19</date>
          <desc>
            <address>
              <addrLine>INSU-CNRS3 rue Michel-Ange, 75794 Paris Cedex 16</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.insu.cnrs.fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-300297" status="VALID">
          <idno type="IdRef">026402971</idno>
          <idno type="ISNI">0000 0001 2158 1666</idno>
          <idno type="ROR">https://ror.org/014zrew76</idno>
          <orgName>Université d'Orléans</orgName>
          <orgName type="acronym">UO</orgName>
          <desc>
            <address>
              <addrLine>Château de la Source - Avenue du Parc Floral - BP 6749 - 45067 Orléans cedex 2</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-orleans.fr/</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-458369" status="VALID">
          <idno type="ROR">https://ror.org/04h1h0y33</idno>
          <orgName>Centre National d’Études Spatiales [Paris]</orgName>
          <orgName type="acronym">CNES</orgName>
          <desc>
            <address>
              <addrLine>Siège social : 2 place Maurice Quentin, 75039 Paris</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://cnes.fr/fr</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-474627" status="VALID">
          <idno type="IdRef">232435111</idno>
          <idno type="ISNI">0000000405066498</idno>
          <idno type="ROR">https://ror.org/00s19x989</idno>
          <orgName>Institut des Sciences de l'Ingénierie et des Systèmes - CNRS Ingénierie</orgName>
          <orgName type="acronym">INSIS - CNRS</orgName>
          <date type="start">2009-11-01</date>
          <desc>
            <address>
              <addrLine>3 rue Michel-Ange, 75794, Paris cedex 16, France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.insis.cnrs.fr/fr</ref>
          </desc>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>