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Article Dans Une Revue Coordination Chemistry Reviews Année : 2022

Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes

Résumé

Rapidly emerging application of organometallic manganese complexes incorporating less elaborated mono- and bidentate donor ligands in catalytic hydrogenation, transfer hydrogenation, hydrogen-borrowing and hydrosilylation processes is comprehensively reviewed. Special attention is devoted to the influence of the nature of donor moieties (P-, N- and C-donors) on the catalytic activity and/or selectivity, the comparison with structurally related polydentate systems and mechanistic aspects.
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hal-03566299 , version 1 (11-02-2022)

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Ekaterina S Gulyaeva, Elena S Osipova, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais, et al.. Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes. Coordination Chemistry Reviews, 2022, 458, pp.214421. ⟨10.1016/j.ccr.2022.214421⟩. ⟨hal-03566299⟩
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