Towards ligand simplification in manganese-catalyzed hydrogenation and hydrosilylation processes
Abstract
Rapidly emerging application of organometallic manganese complexes incorporating less elaborated mono- and bidentate donor ligands in catalytic hydrogenation, transfer hydrogenation, hydrogen-borrowing and hydrosilylation processes is comprehensively reviewed. Special attention is devoted to the influence of the nature of donor moieties (P-, N- and C-donors) on the catalytic activity and/or selectivity, the comparison with structurally related polydentate systems and mechanistic aspects.
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