In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol - Archive ouverte HAL Access content directly
Journal Articles Nanomaterials Year : 2022

In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol

Lauriane Bruna
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Vincent Colliere
Karine Philippot
M. Rosa Axet

Abstract

Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 °C under 20 bar of H2 pressure.
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hal-03562651 , version 1 (09-02-2022)

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Lauriane Bruna, Miquel Cardona-Farreny, Vincent Colliere, Karine Philippot, M. Rosa Axet. In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol. Nanomaterials, 2022, 12 (3), pp.328. ⟨10.3390/nano12030328⟩. ⟨hal-03562651⟩
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