Swelling of a Lyotropic Hexagonal Phase by Monitoring the Radius of the Cylinders - Archive ouverte HAL
Article Dans Une Revue Langmuir Année : 1997

Swelling of a Lyotropic Hexagonal Phase by Monitoring the Radius of the Cylinders

Pascale Fabre

Résumé

We report the elaboration of a lyotropic hexagonal mesophase with a very large lattice parameter. The quaternary system studied displays a hexagonal phase of direct type, namely, nonpolar tubes in a polar medium:  by varying the ionic force of the polar medium, i.e., by addition of salt, we show that it is possible to realize hexagonal mesophases with swollen cylinders of monitored radius up to 17 nm. Moreover, from microscopic observations we have access to the elastic characteristics of the swollen lyotropic hexagonal phases, quantified by a penetration length λ. We find that λ increases with the swelling ratio and interpret this result via microscopic models.

Dates et versions

hal-03557111 , version 1 (04-02-2022)

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Laurence Ramos, Pascale Fabre. Swelling of a Lyotropic Hexagonal Phase by Monitoring the Radius of the Cylinders. Langmuir, 1997, 13 (4), pp.682-686. ⟨10.1021/la9607060⟩. ⟨hal-03557111⟩

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