Corrosion Damages Induced by Cyclic Exposure of 2024 Aluminum Alloy in Chloride-Containing Environments - Archive ouverte HAL
Article Dans Une Revue Journal of The Electrochemical Society Année : 2011

Corrosion Damages Induced by Cyclic Exposure of 2024 Aluminum Alloy in Chloride-Containing Environments

Résumé

This paper focuses on the influence of cyclic exposure to chloride solutions on corrosion damage morphology developed on AA2024. The influence of the temperature during the air exposure periods was studied. Cyclic corrosion tests led to enhanced global corrosion damage compared to continuous immersion tests with residual mechanical properties of corroded samples significantly lower for cyclic tests. The corrosion morphology depended on the exposure conditions. For cyclic tests with air exposure periods at room temperature (CR tests), the corrosion defects were significantly longer; for a cyclic test with air exposure periodsat -20 °C (CF tests), the propagation of corrosion defects was not promoted; however, the density of corroded grain boundaries was markedly increased. For CR samples, the corrosion damage observed was mainly explained taking into account electrochemical processes occurring at the tip of the defect which could be considered as an occluded zone characterized by a chloride-enriched electrolyte and Hþ reduction as major cathodic reaction. For CF tests, the interaction between the stresses induced by the phase transformation of the medium i.e solidification and the hydrogen enrichment of the substrate could be a possible mechanism explaining the evolution of the global mechanical properties of the corroded samples

Domaines

Matériaux
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Dates et versions

hal-03542106 , version 1 (25-01-2022)

Identifiants

Citer

Céline Larignon, Joël Alexis, Eric Andrieu, Christine Blanc, Grégory Odemer, et al.. Corrosion Damages Induced by Cyclic Exposure of 2024 Aluminum Alloy in Chloride-Containing Environments. Journal of The Electrochemical Society, 2011, 158 (6), pp.C284-C295. ⟨10.1149/1.3610401⟩. ⟨hal-03542106⟩
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