Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold
Résumé
Upon coordination of Mes 2 PC(CHPh)Al t Bu 2 , bridging P→M–Cl→Al coordination was observed with Rh and Pd fragments, while chloride abstraction occurred with Au. The resulting zwitterionic complexes have been fully characterized and analyzed by DFT calculations.