Catalytic membrane reactor for Suzuki-Miyaura C-C cross-coupling: Explanation for its high efficiency via modeling - Archive ouverte HAL Access content directly
Journal Articles AIChE Journal Year : 2017

Catalytic membrane reactor for Suzuki-Miyaura C-C cross-coupling: Explanation for its high efficiency via modeling

Abstract

A polymeric catalytic membrane was previously prepared that showed remarkable efficiency for Suzuki-Miyaura C-C cross-coupling in a flow-through configuration. A mathematic model was developed and fitted to the experimental data to understand the significant apparent reaction rate increase exhibited by the catalytic membrane reactor compared to the catalytic system under batch reaction conditions. It appears that the high palladium nanoparticles concentration inside the membrane is mainly responsible for the high apparent reaction rate achieved. In addition the best performance of the catalytic membrane could be achieved only in the forced flow-through configuration, that, conditions permitting to the reactants be brought to the catalytic membrane by convection.
Fichier principal
Vignette du fichier
Gu_15959.pdf (260.92 Ko) Télécharger le fichier
Origin Files produced by the author(s)

Dates and versions

hal-03514551 , version 1 (06-01-2022)

Identifiers

Cite

Yingying Gu, Patrice Bacchin, Isabelle Favier, Douglas L. Gin, Jean-Francois Lahitte, et al.. Catalytic membrane reactor for Suzuki-Miyaura C-C cross-coupling: Explanation for its high efficiency via modeling. AIChE Journal, 2017, 63 (2), pp.698-704. ⟨10.1002/aic.15379⟩. ⟨hal-03514551⟩
21 View
10 Download

Altmetric

Share

Gmail Mastodon Facebook X LinkedIn More