Dinitrogen-derived (diarylboryl)diazenido Complexes with Differing Coordination to the Thallium Cation - Archive ouverte HAL Access content directly
Journal Articles Dalton Transactions Year : 2022

Dinitrogen-derived (diarylboryl)diazenido Complexes with Differing Coordination to the Thallium Cation

Abstract

To prepare N2-derived cationic boryldiazenido-tungsten complexes as models of semimetallic metal-borinium frustrated Lewis pairs activating N2, we have attempted halide abstraction from trans-(diarylboryl)diazenido-halo-tungsten complexes. Reactions with Tl+ led to adducts in which coordination of the cation differs depending on the boryldiazenide substituents and the ancillary ligand. Chloride scavenging was not observed.
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Dates and versions

hal-03474760 , version 1 (10-12-2021)

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Amal Bouammali, Anaïs Coffinet, Laure Vendier, Antoine Simonneau. Dinitrogen-derived (diarylboryl)diazenido Complexes with Differing Coordination to the Thallium Cation. Dalton Transactions, 2022, 51 (28), pp.10697-10701. ⟨10.1039/D1DT03905A⟩. ⟨hal-03474760⟩
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