Despite dissolved carbon (C) exports from continents being crucial in the connection between terrestrial, atmospheric and oceanic C pools, the relative contribution and process controls on dissolved organic (DOC) and inorganic (DIC) fluxes within river basins are not fully understood. This paper presents an analysis of data from 843 sites worldwide from 45 Web of Science SCI-Expanded (ex ISI) indexed papers that report both the DOC and DIC contents and fluxes in conjunction with chemical elements, such as Si, Na and 13C abundance, to investigate the likely origin, pathways and fate of the dissolved C. The reviewed papers also report on selected environmental factors (e.g., MAP and MAT: mean annual precipitation and temperature respectively; Climate, LU: land use, A: basin surface area). Regarding dissolved C fluxes rivers transported on average, 8.4 GT C yr−1 of dissolved C with 7.7 GT C yr−1 (92%) being DIC and remaining (8%) DOC. Asia has the highest within-river dissolved C transport (5.8 GT C yr−1) followed by Europe (2.0 GT C yr−1), America (0.4 GT C yr−1), and Africa (0.1 GT C yr−1). The dissolved C fluxes tend to increase with river water fluxes and contribution of interflow as seen in the tropical climate, which results in the export of relatively fresh DOC with low aromaticity. In contrast, the lower river water fluxes in sub-tropical and temperate climates corresponds to high concentration of comparatively more decomposed DOC, which pointed to a high proportion of groundwater contribution to the water fluxes. The results also imply that surface area and morphology of the river basins, as well as land use, has insignificant impact on dissolved C dynamics. Such quantitative results, including on the important role of climate on the dynamics of dissolved C in river basins, are helpful in improving predictions on the impact of climate change on the global C cycle. New and innovative multidisciplinary research on the subject is called for.