Rheological, electrical, and dynamic thermomechanical properties: Comparison between multiwall and double-wall carbon nanotubes in polylactide and polyamide 11 - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Physics of Fluids Année : 2021

Rheological, electrical, and dynamic thermomechanical properties: Comparison between multiwall and double-wall carbon nanotubes in polylactide and polyamide 11

Zeinab Mousavi
Marie-Claude Heuzey
  • Fonction : Auteur
Musa R Kamal
  • Fonction : Auteur
Pierre J Carreau
  • Fonction : Auteur
  • PersonId : 1138864

Résumé

In this study, multiwall carbon nanotubes (MWCNTs) and double-wall carbon nanotubes (DWCNTs) have been dispersed in polylactide (PLA) and polyamide 11 (PA11) using an internal mixer. Rheological characterization confirmed the formation of carbon nanotube (CNT) networks in PLA and PA11 attributed to well-dispersed CNTs in the respective matrices. A lower rheological percolation threshold of PLA/ MWCNT nanocomposites (less than 0.5 wt. %) compared to PA11/MWCNT nanocomposites (about 2 wt. %) confirmed the greater affinity of CNTs for PLA. The threshold for DWCNTs was below 0.5 wt. % in PLA and between 0.5 and 1 wt. % in PA11. PLA-based nanocomposites also showed higher electrical conductivity values compared to PA11-based nanocomposites. Nanocomposites containing DWCNTs exhibited higher electrical conductivities compared to those containing MWCNTs due to the higher aspect ratio of DWCNTs. Dynamic mechanical thermal analysis showed enhanced storage modulus values and reduced damping behavior with increasing content of CNTs for both polymers.

Domaines

Matériaux
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Dates et versions

hal-03427412 , version 1 (17-11-2021)

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Citer

Zeinab Mousavi, Marie-Claude Heuzey, Musa R Kamal, Emmanuel Flahaut, Pierre J Carreau. Rheological, electrical, and dynamic thermomechanical properties: Comparison between multiwall and double-wall carbon nanotubes in polylactide and polyamide 11. Physics of Fluids, 2021, 33 (11), pp.113103. ⟨10.1063/5.0068537⟩. ⟨hal-03427412⟩
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