Synthesis of axially chiral biaryl thioglycosides through thiosugar-directed Pd-catalyzed asymmetric C–H activation - Archive ouverte HAL
Article Dans Une Revue Chemical Communications Année : 2021

Synthesis of axially chiral biaryl thioglycosides through thiosugar-directed Pd-catalyzed asymmetric C–H activation

Résumé

An atroposelective Fujiwara–Moritani reaction towards the synthesis of alkenylthioglycoside is reported. β-thioglucose moiety is used both as a directing group for the C–H bond activation and as a chiral source inducing axial chirality.

Domaines

Chimie
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Dates et versions

hal-03425421 , version 1 (10-11-2021)

Identifiants

Citer

Maha Fatthalla, Nicolas Grimblat, Etienne Brachet, Mouad Alami, Vincent Gandon, et al.. Synthesis of axially chiral biaryl thioglycosides through thiosugar-directed Pd-catalyzed asymmetric C–H activation. Chemical Communications, 2021, 57 (80), pp.10355-10358. ⟨10.1039/d1cc03971g⟩. ⟨hal-03425421⟩
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