Aromatic Trifluoromethylselenolation via Pd-catalyzed C-H functionalization
Résumé
The synthesis of trifluoromethylselenolated aromatic molecules is described via an auxiliary-assisted, palladium catalyzed, C-H bonds functionalization with trifluoromethyl tolueneselenosulfonate as reagent. The mono-or bis-products can be preferentially formed. Some mechanistic investigations were realized to better understand the reaction. This methodology was also extended to fluoroalkylselenyl groups.
Domaines
Chimie organique| Origine | Fichiers produits par l'(les) auteur(s) |
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