Solvothermal and mechanochemical intercalation of Cu into La 2 O 2 S 2 enabled by the redox reactivity of (S 2 ) 2pairs
Résumé
Intercalation of Cu into layered polychalcogenide La2O2S2 was demonstrated to be viable both in solvothermal condition at 200 °C and mechanical ball milling at ambient temperature. This result evidences the soft-chemical nature of metal intercalation into layered polychalcogenides driven by redox reactivity of anionanion bonds.
Domaines
Chimie inorganique
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Solvo-Mechano intercalation_27072021_final_withouthighlight_HAL-2.pdf (459.99 Ko)
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