Solid-state and solution characterizations of [(TMPA)Cu(II)(SO3)] and [(TMPA)Cu(II)(S2O3)] complexes: Application to sulfite and thiosulfate fast detection - Archive ouverte HAL Access content directly
Journal Articles Journal of Inorganic Biochemistry Year : 2021

Solid-state and solution characterizations of [(TMPA)Cu(II)(SO3)] and [(TMPA)Cu(II)(S2O3)] complexes: Application to sulfite and thiosulfate fast detection

Abstract

Sulfite (SO32−) and thiosulfate (S2O32−) ions are used as food preservative and antichlor agent respectively. To detect low levels of such anions we used Cu(II) complex of the Tris-Methyl Pyridine Amine (TMPA) ligand, denoted L. Formation of [LCu(SO3)] (1) and [LCu(S2O3)] (2) in solution were monitored using UV–Vis, EPR and cyclic voltammetry, while the solid-state X-ray structures of both complexes were solved. In addition, we also evaluated the pH range in which the complexes are stable, and the anions binding affinity values for the [LCu(solvent)]2+ (3) parent complex. As a matter of illustration, we determined the sulfite content in a commercial crystal sugar.
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Dates and versions

hal-03394471 , version 1 (22-10-2021)

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Léonie Berthonnaud, Charlène Esmieu, Sonia Mallet-Ladeira, Christelle Hureau. Solid-state and solution characterizations of [(TMPA)Cu(II)(SO3)] and [(TMPA)Cu(II)(S2O3)] complexes: Application to sulfite and thiosulfate fast detection. Journal of Inorganic Biochemistry, 2021, 225, pp.111601. ⟨10.1016/j.jinorgbio.2021.111601⟩. ⟨hal-03394471⟩
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