Size‐Controlled Hapticity Switching in [Ln(C9H9)(C8H8)] Sandwiches - Archive ouverte HAL
Article Dans Une Revue Chemistry - A European Journal Année : 2021

Size‐Controlled Hapticity Switching in [Ln(C9H9)(C8H8)] Sandwiches

Léo La Droitte
Olivier Cador

Résumé

Sandwich complexes of lanthanides have recently attracted a considerable amount of interest due to their applications as Single Molecule Magnet (SMM). Herein, a comprehensive series of heteroleptic lanthanide sandwich complexes ligated by the cyclononatetraenyl (Cnt) and the cyclooctatetraenyl (Cot) ligand [Ln(Cot)(Cnt)] (Ln=Tb, Dy, Er, Ho, Yb, and Lu) is reported. The coordination behavior of the Cnt ligand has been investigated along the series and shows different coordination patterns in the solid-state depending on the size of the corresponding lanthanide ion without altering its overall anisotropy. Besides the characterization in the solid state by single-crystal X-ray diffraction and in solution by 1 H NMR, static magnetic studies and ab initio computational studies were performed.
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Dates et versions

hal-03380768 , version 1 (15-10-2021)

Identifiants

Citer

Maxime Tricoire, Luca Münzfeld, Jules Moutet, Nolwenn Mahieu, Léo La Droitte, et al.. Size‐Controlled Hapticity Switching in [Ln(C9H9)(C8H8)] Sandwiches. Chemistry - A European Journal, 2021, 27 (54), pp.13558 - 13567. ⟨10.1002/chem.202101599⟩. ⟨hal-03380768⟩
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