<?xml version="1.0" encoding="utf-8"?>
<TEI xmlns="http://www.tei-c.org/ns/1.0" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:hal="http://hal.archives-ouvertes.fr/" xmlns:gml="http://www.opengis.net/gml/3.3/" xmlns:gmlce="http://www.opengis.net/gml/3.3/ce" version="1.1" xsi:schemaLocation="http://www.tei-c.org/ns/1.0 http://api.archives-ouvertes.fr/documents/aofr-sword.xsd">
  <teiHeader>
    <fileDesc>
      <titleStmt>
        <title>HAL TEI export of hal-03378292</title>
      </titleStmt>
      <publicationStmt>
        <distributor>CCSD</distributor>
        <availability status="restricted">
          <licence target="https://creativecommons.org/publicdomain/zero/1.0/">CC0 1.0 - Universal</licence>
        </availability>
        <date when="2026-05-02T15:47:41+02:00"/>
      </publicationStmt>
      <sourceDesc>
        <p part="N">HAL API Platform</p>
      </sourceDesc>
    </fileDesc>
  </teiHeader>
  <text>
    <body>
      <listBibl>
        <biblFull>
          <titleStmt>
            <title xml:lang="en">AB5 Derivatives of Cyclotriphosphazene for the Synthesis of Dendrons and Their Applications</title>
            <author role="aut">
              <persName>
                <forename type="first">Artem</forename>
                <surname>Zibarov</surname>
              </persName>
              <email type="md5">0f9c30adce5349239943487483ccfb02</email>
              <email type="domain">lcc-toulouse.fr</email>
              <idno type="idhal" notation="numeric">1138078</idno>
              <idno type="halauthorid" notation="string">1685516-1138078</idno>
              <affiliation ref="#struct-461"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Abdelouahd</forename>
                <surname>Oukhrib</surname>
              </persName>
              <idno type="halauthorid">1641313-0</idno>
              <affiliation ref="#struct-461"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Julien</forename>
                <surname>Aujard Catot</surname>
              </persName>
              <idno type="halauthorid">2309924-0</idno>
              <affiliation ref="#struct-461"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Cédric-Olivier</forename>
                <surname>Turrin</surname>
              </persName>
              <email type="md5">0ed85610d51e2fc314a90e62b05b655f</email>
              <email type="domain">lcc-toulouse.fr</email>
              <idno type="idhal" notation="string">cedric-olivier-turrin</idno>
              <idno type="idhal" notation="numeric">743943</idno>
              <idno type="halauthorid" notation="string">14450-743943</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-7187-8070</idno>
              <idno type="IDREF">https://www.idref.fr/157747581</idno>
              <affiliation ref="#struct-461"/>
            </author>
            <author role="aut">
              <persName>
                <forename type="first">Anne-Marie</forename>
                <surname>Caminade</surname>
              </persName>
              <email type="md5">0a446e1406ceb080d492e8fabec6da12</email>
              <email type="domain">lcc-toulouse.fr</email>
              <idno type="idhal" notation="string">anne-marie-caminade</idno>
              <idno type="idhal" notation="numeric">738695</idno>
              <idno type="halauthorid" notation="string">3637-738695</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/E-2819-2015</idno>
              <idno type="ORCID">https://orcid.org/0000-0001-8487-3578</idno>
              <idno type="IDREF">https://www.idref.fr/033572089</idno>
              <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/E-2819-2015</idno>
              <affiliation ref="#struct-461"/>
            </author>
            <editor role="depositor">
              <persName>
                <forename>Marie-Hélène</forename>
                <surname>Gulli</surname>
              </persName>
              <email type="md5">3cb87f89132640b4fa8a819ffd202dda</email>
              <email type="domain">lcc-toulouse.fr</email>
            </editor>
            <funder ref="#projanr-42951"/>
            <funder>CNRS</funder>
          </titleStmt>
          <editionStmt>
            <edition n="v1" type="current">
              <date type="whenSubmitted">2021-10-14 15:33:39</date>
              <date type="whenModified">2025-10-22 18:04:08</date>
              <date type="whenReleased">2021-10-14 15:40:20</date>
              <date type="whenProduced">2021</date>
              <date type="whenEndEmbargoed">2021-10-14</date>
              <ref type="file" target="https://hal.science/hal-03378292v1/document">
                <date notBefore="2021-10-14"/>
              </ref>
              <ref type="file" subtype="greenPublisher" n="1" target="https://hal.science/hal-03378292v1/file/molecules-26-04017-v2.pdf" id="file-3378292-2965998">
                <date notBefore="2021-10-14"/>
              </ref>
              <ref type="externalLink" target="https://www.mdpi.com/1420-3049/26/13/4017/pdf"/>
            </edition>
            <respStmt>
              <resp>contributor</resp>
              <name key="194368">
                <persName>
                  <forename>Marie-Hélène</forename>
                  <surname>Gulli</surname>
                </persName>
                <email type="md5">3cb87f89132640b4fa8a819ffd202dda</email>
                <email type="domain">lcc-toulouse.fr</email>
              </name>
            </respStmt>
          </editionStmt>
          <publicationStmt>
            <distributor>CCSD</distributor>
            <idno type="halId">hal-03378292</idno>
            <idno type="halUri">https://hal.science/hal-03378292</idno>
            <idno type="halBibtex">zibarov:hal-03378292</idno>
            <idno type="halRefHtml">&lt;i&gt;Molecules&lt;/i&gt;, 2021, 26 (13), pp.4017. &lt;a target="_blank" href="https://dx.doi.org/10.3390/molecules26134017"&gt;&amp;#x27E8;10.3390/molecules26134017&amp;#x27E9;&lt;/a&gt;</idno>
            <idno type="halRef">Molecules, 2021, 26 (13), pp.4017. &amp;#x27E8;10.3390/molecules26134017&amp;#x27E9;</idno>
            <availability status="restricted">
              <licence target="https://creativecommons.org/licenses/by/4.0/">CC BY 4.0 - Attribution<ref corresp="#file-3378292-2965998"/></licence>
            </availability>
          </publicationStmt>
          <seriesStmt>
            <idno type="stamp" n="IRD">IRD - Institut de recherche pour le développement</idno>
            <idno type="stamp" n="UNIV-TLSE3">Université de Toulouse</idno>
            <idno type="stamp" n="CNRS">CNRS - Centre national de la recherche scientifique</idno>
            <idno type="stamp" n="LCC">Laboratoire de Chimie de Coordination UPR8241</idno>
            <idno type="stamp" n="INC-CNRS">Institut de Chimie du CNRS</idno>
            <idno type="stamp" n="TEST-HALCNRS">Collection test HAL CNRS</idno>
            <idno type="stamp" n="ANR">ANR</idno>
            <idno type="stamp" n="TOULOUSE-INP">Toulouse - INP</idno>
            <idno type="stamp" n="UNIV-UT3">Université Toulouse 3</idno>
            <idno type="stamp" n="UT3-INP">Université de Toulouse / Toulouse INP</idno>
            <idno type="stamp" n="UT3-TOULOUSEINP">Université de Toulouse / Toulouse INP</idno>
            <idno type="stamp" n="TEST2-HALCNRS">TEST2-HALCNRS</idno>
            <idno type="stamp" n="ICT-CHIMIE">ICT-CHIMIE </idno>
          </seriesStmt>
          <notesStmt>
            <note type="audience" n="2">International</note>
            <note type="popular" n="0">No</note>
            <note type="peer" n="1">Yes</note>
          </notesStmt>
          <sourceDesc>
            <biblStruct>
              <analytic>
                <title xml:lang="en">AB5 Derivatives of Cyclotriphosphazene for the Synthesis of Dendrons and Their Applications</title>
                <author role="aut">
                  <persName>
                    <forename type="first">Artem</forename>
                    <surname>Zibarov</surname>
                  </persName>
                  <email type="md5">0f9c30adce5349239943487483ccfb02</email>
                  <email type="domain">lcc-toulouse.fr</email>
                  <idno type="idhal" notation="numeric">1138078</idno>
                  <idno type="halauthorid" notation="string">1685516-1138078</idno>
                  <affiliation ref="#struct-461"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Abdelouahd</forename>
                    <surname>Oukhrib</surname>
                  </persName>
                  <idno type="halauthorid">1641313-0</idno>
                  <affiliation ref="#struct-461"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Julien</forename>
                    <surname>Aujard Catot</surname>
                  </persName>
                  <idno type="halauthorid">2309924-0</idno>
                  <affiliation ref="#struct-461"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Cédric-Olivier</forename>
                    <surname>Turrin</surname>
                  </persName>
                  <email type="md5">0ed85610d51e2fc314a90e62b05b655f</email>
                  <email type="domain">lcc-toulouse.fr</email>
                  <idno type="idhal" notation="string">cedric-olivier-turrin</idno>
                  <idno type="idhal" notation="numeric">743943</idno>
                  <idno type="halauthorid" notation="string">14450-743943</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-7187-8070</idno>
                  <idno type="IDREF">https://www.idref.fr/157747581</idno>
                  <affiliation ref="#struct-461"/>
                </author>
                <author role="aut">
                  <persName>
                    <forename type="first">Anne-Marie</forename>
                    <surname>Caminade</surname>
                  </persName>
                  <email type="md5">0a446e1406ceb080d492e8fabec6da12</email>
                  <email type="domain">lcc-toulouse.fr</email>
                  <idno type="idhal" notation="string">anne-marie-caminade</idno>
                  <idno type="idhal" notation="numeric">738695</idno>
                  <idno type="halauthorid" notation="string">3637-738695</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/E-2819-2015</idno>
                  <idno type="ORCID">https://orcid.org/0000-0001-8487-3578</idno>
                  <idno type="IDREF">https://www.idref.fr/033572089</idno>
                  <idno type="RESEARCHERID">http://www.researcherid.com/rid/http://www.researcherid.com/rid/E-2819-2015</idno>
                  <affiliation ref="#struct-461"/>
                </author>
              </analytic>
              <monogr>
                <idno type="halJournalId" status="VALID">17196</idno>
                <idno type="issn">1420-3049</idno>
                <title level="j">Molecules</title>
                <imprint>
                  <publisher>MDPI</publisher>
                  <biblScope unit="volume">26</biblScope>
                  <biblScope unit="issue">13</biblScope>
                  <biblScope unit="pp">4017</biblScope>
                  <date type="datePub">2021</date>
                </imprint>
              </monogr>
              <idno type="doi">10.3390/molecules26134017</idno>
            </biblStruct>
          </sourceDesc>
          <profileDesc>
            <langUsage>
              <language ident="en">English</language>
            </langUsage>
            <textClass>
              <keywords scheme="author">
                <term xml:lang="en">Nanomedicine</term>
                <term xml:lang="en">Catalysis</term>
                <term xml:lang="en">Sensors</term>
                <term xml:lang="en">Nanomaterials</term>
                <term xml:lang="en">Dendrimer</term>
                <term xml:lang="en">Phosphorus</term>
                <term xml:lang="en">DendronFluorescence</term>
                <term xml:lang="en">Cyclotriphosphazene</term>
              </keywords>
              <classCode scheme="halDomain" n="chim.coor">Chemical Sciences/Coordination chemistry</classCode>
              <classCode scheme="halDomain" n="chim.poly">Chemical Sciences/Polymers</classCode>
              <classCode scheme="halTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halOldTypology" n="ART">Journal articles</classCode>
              <classCode scheme="halTreeTypology" n="ART">Journal articles</classCode>
            </textClass>
            <abstract xml:lang="en">
              <p>AB5 compounds issued from the reactivity of hexachlorocyclotriphosphazene are relatively easy to obtain using two ways: either first the reaction of one chloride with one reagent, followed by the reaction of the five remaining Cl with another reagent, or first the reaction of five chlorides with one reagent, followed by the reaction of the single remaining Cl with another reagent. This particular property led to the use of such compounds as core for the synthesis of dendrons (dendritic wedges), using the five functions for growing the dendritic branches. The single function can be used for the synthesis of diverse types of dendrimers (onion peel, dumbbell-shape, Janus), for covalent or non-covalent grafting to solid surfaces, providing nanomaterials, for grafting a fluorophore, especially for studying biological mechanisms, or for self-associations to get micelles. All these properties are reviewed in this paper.</p>
            </abstract>
          </profileDesc>
        </biblFull>
      </listBibl>
    </body>
    <back>
      <listOrg type="structures">
        <org type="laboratory" xml:id="struct-461" status="OLD">
          <idno type="IdRef">190242221</idno>
          <idno type="ISNI">0000 0004 0638 384X</idno>
          <idno type="RNSR">197417418A</idno>
          <idno type="ROR">https://ror.org/01rtzw447</idno>
          <orgName>Laboratoire de chimie de coordination</orgName>
          <orgName type="acronym">LCC</orgName>
          <date type="start">1974-01-01</date>
          <date type="end">2025-01-01</date>
          <desc>
            <address>
              <addrLine>205 Route de Narbonne 31077 TOULOUSE CEDEX 4</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.lcc-toulouse.fr</ref>
          </desc>
          <listRelation>
            <relation active="#struct-159253" type="direct"/>
            <relation active="#struct-67872" type="indirect"/>
            <relation active="#struct-217752" type="direct"/>
            <relation active="#struct-443875" type="indirect"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UAR2599 / FR2599" active="#struct-441569" type="direct"/>
            <relation active="#struct-448187" type="direct"/>
            <relation name="UPR8241" active="#struct-441569" type="direct"/>
          </listRelation>
        </org>
        <org type="regrouplaboratory" xml:id="struct-159253" status="OLD">
          <idno type="IdRef">240309472</idno>
          <idno type="ISNI">0000 0004 4686 8315</idno>
          <idno type="RNSR">200310667L</idno>
          <orgName>Institut de Chimie de Toulouse</orgName>
          <orgName type="acronym">ICT</orgName>
          <date type="end">2025-01-01</date>
          <desc>
            <address>
              <addrLine>118 Route de Narbonne 31062 Toulouse cédex 9</addrLine>
              <country key="FR"/>
            </address>
          </desc>
          <listRelation>
            <relation active="#struct-67872" type="direct"/>
            <relation active="#struct-217752" type="direct"/>
            <relation active="#struct-443875" type="indirect"/>
            <relation active="#struct-341038" type="direct"/>
            <relation name="UAR2599 / FR2599" active="#struct-441569" type="direct"/>
            <relation active="#struct-448187" type="direct"/>
          </listRelation>
        </org>
        <org type="institution" xml:id="struct-67872" status="VALID">
          <idno type="IdRef">050165224</idno>
          <idno type="ROR">https://ror.org/05q3vnk25</idno>
          <orgName>Institut de Recherche pour le Développement</orgName>
          <orgName type="acronym">IRD</orgName>
          <desc>
            <address>
              <addrLine>SiègeLe Sextant 44, bd de DunkerqueCS 9000913572 Marseille cedex 02</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.ird.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-217752" status="OLD">
          <idno type="IdRef">026404672</idno>
          <idno type="ISNI">0000000121617331</idno>
          <idno type="ROR">https://ror.org/02v6kpv12</idno>
          <idno type="Wikidata">Q1273188</idno>
          <orgName>Université Toulouse III - Paul Sabatier</orgName>
          <orgName type="acronym">UT3</orgName>
          <date type="end">2025-01-01</date>
          <desc>
            <address>
              <addrLine>118 route de Narbonne - 31062 Toulouse</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.univ-tlse3.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-443875" type="direct"/>
          </listRelation>
        </org>
        <org type="regroupinstitution" xml:id="struct-443875" status="VALID">
          <idno type="ROR">https://ror.org/017tgbk05</idno>
          <orgName>Communauté d'universités et établissements de Toulouse</orgName>
          <orgName type="acronym">Comue de Toulouse</orgName>
          <desc>
            <address>
              <addrLine>41 Allée Jules Guesde, 31000 Toulouse</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.univ-toulouse.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-341038" status="VALID">
          <idno type="IdRef">232435103</idno>
          <idno type="ISNI">000000010626358X</idno>
          <idno type="ROR">https://ror.org/02cte4b68</idno>
          <orgName>Institut de Chimie - CNRS Chimie</orgName>
          <orgName type="acronym">INC-CNRS</orgName>
          <date type="start">2009-10-01</date>
          <desc>
            <address>
              <addrLine>CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE3 rue Michel-Ange75794 PARIS CEDEX 16 - France</addrLine>
              <country key="FR"/>
            </address>
            <ref type="url">http://www.cnrs.fr/inc</ref>
          </desc>
        </org>
        <org type="regroupinstitution" xml:id="struct-441569" status="VALID">
          <idno type="IdRef">02636817X</idno>
          <idno type="ISNI">0000000122597504</idno>
          <idno type="ROR">https://ror.org/02feahw73</idno>
          <orgName>Centre National de la Recherche Scientifique</orgName>
          <orgName type="acronym">CNRS</orgName>
          <date type="start">1939-10-19</date>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.cnrs.fr/</ref>
          </desc>
        </org>
        <org type="institution" xml:id="struct-448187" status="VALID">
          <idno type="IdRef">026388820</idno>
          <idno type="ISNI">0000000121766169</idno>
          <idno type="ROR">https://ror.org/033p9g875</idno>
          <orgName>Institut National Polytechnique (Toulouse)</orgName>
          <orgName type="acronym">Toulouse INP</orgName>
          <desc>
            <address>
              <country key="FR"/>
            </address>
            <ref type="url">https://www.inp-toulouse.fr/</ref>
          </desc>
          <listRelation>
            <relation active="#struct-443875" type="direct"/>
          </listRelation>
        </org>
      </listOrg>
      <listOrg type="projects">
        <org type="anrProject" xml:id="projanr-42951" status="VALID">
          <idno type="anr">ANR-17-CE09-0001</idno>
          <orgName>SLOW2</orgName>
          <desc>Ecriture en stéréo dans l'eau par un laser</desc>
          <date type="start">2017</date>
        </org>
      </listOrg>
    </back>
  </text>
</TEI>